Formation of ultralow friction surface films on boron carbide

被引:117
作者
Erdemir, A [1 ]
Bindal, C [1 ]
Fenske, GR [1 ]
机构
[1] SAKARYA UNIV,DEPT MET ENGN,ADAPAZARI,TURKEY
关键词
D O I
10.1063/1.115676
中图分类号
O59 [应用物理学];
学科分类号
摘要
In this letter, we describe the formation and ultralow friction mechanisms of a surface film on boron carbide (B4C). This film results from sequential reactions between B4C and oxygen and between the resulting boron oxide (B2O3) and moisture; it can afford friction coefficients of 0.03 to 0.05 to sliding steel surfaces. At temperatures above 600 degrees C, B4C undergoes oxidation and forms a layer of boron oxide (B2O3) in the upper surface. During cooling to room temperature, the B2O3 reacts with moisture in the air to form a secondary him, boric acid (H3BO3) The sliding friction coefficient of 440C steel balls against this film is 0.04, compared to 0.7 against the bare B4C surfaces. Mechanistically, we propose that the ultralow friction behavior of the heat-treated B4C surface is due mainly to the layered-crystal structure of the H3BO3 film that forms on the sliding surface. (C) 1996 American Institute of Physics.
引用
收藏
页码:1637 / 1639
页数:3
相关论文
共 14 条
[1]  
Bindal C, 1996, APPL PHYS LETT, V68, P923, DOI 10.1063/1.116232
[2]   A STUDY OF THE FORMATION AND SELF-LUBRICATION MECHANISMS OF BORIC-ACID FILMS ON BORIC OXIDE COATINGS [J].
ERDEMIR, A ;
FENSKE, GR ;
ERCK, RA .
SURFACE & COATINGS TECHNOLOGY, 1990, 43-4 (1-3) :588-596
[3]  
ERDEMIR A, 1991, LUBR ENG, V47, P168
[4]  
ERDEMIR A, 1991, LUBR ENG, V47, P179
[5]   TRIBOCHEMICAL INTERACTIONS OF BORON CARBIDES AGAINST STEEL [J].
GOGOTSI, YG ;
KOVALCHENKO, AM ;
KOSSKO, IA .
WEAR, 1992, 154 (01) :133-140
[6]  
Halverson D.C., 1985, P CER ENG SCI AM CER, P736
[7]  
JANDA R, 1981, SPECTROCHIM ACTA A, V36, P997
[8]   INFLUENCE OF OXIDATION ON THE COMPOSITION AND STRUCTURE OF THE SURFACE-LAYER OF HOT-PRESSED BORON-CARBIDE [J].
LAVRENKO, VA ;
GOGOTSI, YG .
OXIDATION OF METALS, 1988, 29 (3-4) :193-202
[9]   OXIDATION BEHAVIOR AND STRENGTH OF B4C-30 WT PERCENT SIC COMPOSITE-MATERIALS [J].
RIU, DH ;
CHOI, R ;
KIM, HE ;
KANG, ES .
JOURNAL OF MATERIALS SCIENCE, 1995, 30 (15) :3897-3902
[10]  
THEVENOT F, 1984, J NUCL MATER, V152, P154