Supramolecular structure of {C6H2[CH2OCH2C(pz)3]4[Mn(CO)3]4}(BF4)4 based on tetrametallic organometallic building blocks constructed from a multitopic tris(pyrazolyl)methane ligand

被引:52
作者
Reger, DL [1 ]
Semeniuc, RF [1 ]
Smith, MD [1 ]
机构
[1] Univ S Carolina, Dept Chem & Biochem, Columbia, SC 29208 USA
来源
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2002年 / 04期
关键词
D O I
10.1039/b110095e
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The compound {C6H2[CH2OCH2C(pz)(3)](4)[Mn(CO)(3)](4)}(BF4)(4) forms a 3D sinusoidal architecture with 16 x 7 Angstrom channels organized by pi-pi stacking and weak C-H...F hydrogen bonds.
引用
收藏
页码:476 / 477
页数:2
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