Cationic hydrogels for toxic arsenate removal from aqueous environment

被引:90
作者
Barakat, M. A. [1 ]
Sahiner, Nurettin [2 ]
机构
[1] Cent Met R&D Inst, Cairo 11421, Egypt
[2] Univ Delaware, Dept Mat Sci & Engn, Newark, DE 19716 USA
关键词
hydrogels; water; swelling; environments; arsenic; absorption; removal;
D O I
10.1016/j.jenvman.2007.05.003
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Poly(3-acrylamidopropyl)trimethylammonium chloride (p(AFTMACl)) hydrogels were synthesized and utilized as absorbents for the removal of toxic arsenate from aqueous medium. The pH-dependent swelling characteristics of the hydrogel were studied, and the experimental Parameters that affect the absorption efficiency were investigated. Our results demonstrate that these types of hydrogels are highly effective in removing arsenate(V) anions from the aqueous environment. A removal efficiency of approximately 99.7%, was obtained be immersing 1.5 g/l hydrogel in a solution containing 50 ppm As(V) at pH 9 for 360 min. Moreover, the hydrogels are very easy to handle upon absorption, avoiding issues related to the separation of traditional powder absorbents from water after absorption. (C) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码:955 / 961
页数:7
相关论文
共 25 条
[1]   Removal of arsenic from groundwater by granular titanium dioxide adsorbent [J].
Bang, S ;
Patel, M ;
Lippincott, L ;
Meng, XG .
CHEMOSPHERE, 2005, 60 (03) :389-397
[2]  
Barakat M.A., 2004, J APPL CATAL B, V57, P23
[3]   Removal of hexavalent chromium from wastewater using a new composite chitosan biosorbent [J].
Boddu, VM ;
Abburi, K ;
Talbott, JL ;
Smith, ED .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2003, 37 (19) :4449-4456
[4]   Bioerodible hydrogels based on 2-hydroxyethyl methacrylate: Synthesis and characterization [J].
Chiellini, F ;
Petrucci, F ;
Ranucci, E ;
Solaro, R .
JOURNAL OF APPLIED POLYMER SCIENCE, 2002, 85 (13) :2729-2741
[5]  
Clifford DA, 2002, BOOK SOIL P, P217
[6]   Arsenic removal using polymer-supported hydrated iron(III) oxide nanoparticles: Role of Donnan membrane effect [J].
Cumbal, L ;
Sengupta, AK .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2005, 39 (17) :6508-6515
[7]   Arsenic removal using a polymeric/inorganic hybrid sorbent [J].
DeMarco, MJ ;
Sengupta, AK ;
Greenleaf, JE .
WATER RESEARCH, 2003, 37 (01) :164-176
[8]   Anion exchange fibers for arsenate removal derived from a vinylbenzyl chloride precursor [J].
Dominguez, L ;
Economy, J ;
Benak, K ;
Mangun, CL .
POLYMERS FOR ADVANCED TECHNOLOGIES, 2003, 14 (09) :632-637
[9]  
Gan DJ, 2001, J AM CHEM SOC, V123, P7511, DOI 10.1021/ja010609f
[10]  
Grobosch T, 1996, CHEM TECH-LEIPZIG, V48, P203