Palladium(II)-catalyzed carboxylation of benzene and other aromatic compounds with carbon monoxide under very mild conditions

被引：86

作者：

Lu, WJ

Yamaoka, Y

Taniguchi, Y

Kitamura, T

Takaki, K

Fujiwara, Y ^{[1
]}

机构：

[1] Kyushu Univ, Grad Sch Engn, Dept Chem & Biochem, Fukuoka 8128581, Japan

[2] Hiroshima Univ, Fac Engn, Dept Appl Chem, Higashihiroshima 7398257, Japan

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1999年 / 580卷 / 02期

关键词：

palladium; carbon monoxide; carboxylation; aromatic compounds;

D O I：

10.1016/S0022-328X(98)01160-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Aromatic compounds such as benzene, toluene, chlorobenzene, anisole, and naphthalene were carboxylated by palladium(II) acetate catalyst with carbon monoxide in the presence of potassium peroxodisulfate in trifluoroacetic acid (TFA) at room temperature under atmospheric pressure. The aromatic carboxylic acids were formed in good yields; for example, the carboxylation of benzene with carbon monoxide proceeds quantitatively under the optimal conditions. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：290 / 294

页数：5

共 12 条

[1]

Asadullah M, 1998, APPL ORGANOMET CHEM, V12, P277

[2] ASPECTS OF METHANE CHEMISTRY [J].