Aromatic stacking in folded architectures through hydrogen bonding

被引：6

作者：

Chen, YS ^{[1
]}

Kampf, JW ^{[1
]}

Lawton, RG ^{[1
]}

机构：

[1] UNIV MICHIGAN,DEPT CHEM,ANN ARBOR,MI 48109

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 33期

关键词：

D O I：

10.1016/S0040-4039(97)01318-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The alpha, alpha'-annelation of the enamine of 1,3-hydro-2-phenalenone with methyl alpha-(bromomethyl)acrylate affords an aromatic bicyclic framework, methyl 8,9,10,11-tetrahydro-7,11-methano-12-keto-7H-cyclooocta(de)naphthalene-9-endo-carboxylate having the ester function positioned over the aromatic ring. The acid derivatives of this framework dimerize affording a ''sandwich'' structure with the H-bonded carboxyl groups between parallel naphthalene rings. The dimeric association can be easily probed using both NMR and fluorescence techniques. (C) 1997 Elsevier Science Ltd.

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页码：5781 / 5784

页数：4

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