A new type of entanglement involving one-dimensional ribbons of rings catenated to a three-dimensional network in the nanoporous structure of [Co(bix)2(H2O)2](SO4)•7H2O[bix=1,4-bis(imidazol-1-ylmethyl)benzene]

被引：247

作者：

Carlucci, L ^{[1
]}

Ciani, G ^{[1
]}

Proserpio, DM ^{[1
]}

机构：

[1] Dipartimento Chim Strutturale & Stereochim Inorga, I-20133 Milan, Italy

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 04期

关键词：

D O I：

10.1039/b314322h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Co-II sulfate reacts with the flexible ligand 1,4-bis(imidazol-1-ylmethyl)benzene (bix) to yield the coordination network [Co(bix)(2)(H2O)(2)](SO4).7H(2)O, containing polymeric ribbons of rings which penetrate and catenate a 3D single frame of the CdSO4 topology, to produce an open-channel entangled architecture with nanoporous behaviour.

引用

页码：380 / 381

页数：2

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