Dual electroluminescence from a single-component light-emitting electrochemical cell, based on water-soluble conjugated polymer

被引:35
作者
Gu, Z
Shen, QD [1 ]
Zhang, J
Yang, CZ
Bao, YJ
机构
[1] Nanjing Univ, Dept Polymer Sci & Engn, Nanjing 210093, Peoples R China
[2] Nanjing Univ, Key Lab Mesoscop Chem MOE, Coll Chem & Chem Engn, Nanjing 210093, Peoples R China
[3] Nanjing Univ, Natl Lab Solid State Microstruct, Nanjing 210093, Peoples R China
关键词
MPS-PPV; water-soluble polymer; conjugated polymer; luminescence; single-component light-emitting electrochemical cell;
D O I
10.1002/app.22510
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Poly [[2-methoxy-5-(3-sulfonatopropoxy)-1, 4-phenylenel-1,2-ethenediyl] (MPS-PPV) was an anionic water-soluble conjugated polymer. A novel single-component light-emitting electrochemical cell (LEC) with an indiurn tin oxide/MPS-PPV/aluminum sandwich structure has been successfully fabricated. MPS-PPV serves as both luminescent material and ionic conductor in the active layer. Electroluminescence can be observed under both forward and reverse bias with emission maxima at about 520 nm (green light). In particular, the device has a low turn-on voltage of about +3V and -4V, and can sustain long-term operations without much loss of efficiency at ambient conditions. (c) 2006 Wiley Periodicals, Inc.
引用
收藏
页码:2930 / 2936
页数:7
相关论文
共 29 条
[1]   LIGHT-EMITTING-DIODES BASED ON CONJUGATED POLYMERS [J].
BURROUGHES, JH ;
BRADLEY, DDC ;
BROWN, AR ;
MARKS, RN ;
MACKAY, K ;
FRIEND, RH ;
BURN, PL ;
HOLMES, AB .
NATURE, 1990, 347 (6293) :539-541
[2]   Capacitance measurements of junction formation and structure in polymer light-emitting electrochemical cells [J].
Campbell, IH ;
Smith, DL ;
Neef, CJ ;
Ferraris, JP .
APPLIED PHYSICS LETTERS, 1998, 72 (20) :2565-2567
[3]   Efficient, fast response light-emitting electrochemical cells: Electroluminescent and solid electrolyte polymers with interpenetrating network morphology [J].
Cao, Y ;
Yu, G ;
Heeger, AJ ;
Yang, CY .
APPLIED PHYSICS LETTERS, 1996, 68 (23) :3218-3220
[4]   Dual-color polymer light-emitting pixels processed by hybrid inkjet printing [J].
Chang, SC ;
Bharathan, J ;
Yang, Y ;
Helgeson, R ;
Wudl, F ;
Ramey, MB ;
Reynolds, JR .
APPLIED PHYSICS LETTERS, 1998, 73 (18) :2561-2563
[5]   Highly sensitive biological and chemical sensors based on reversible fluorescence quenching in a conjugated polymer [J].
Chen, LH ;
McBranch, DW ;
Wang, HL ;
Helgeson, R ;
Wudl, F ;
Whitten, DG .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1999, 96 (22) :12287-12292
[6]   New luminescent polymers for LEDs [J].
Chuah, BS ;
Hwang, DH ;
Kim, ST ;
Moratti, SC ;
Holmes, AB ;
De Mello, JC ;
Friend, RH .
SYNTHETIC METALS, 1997, 91 (1-3) :279-282
[7]   Enhanced conjugated polymer fluorescence quenching by dipyridinium-based quenchers in the presence of surfactant [J].
Dalvi-Malhotra, J ;
Chen, LH .
JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (09) :3873-3878
[8]   Interfacial feedback dynamics in polymer light-emitting electrochemical cells [J].
deMello, JC .
PHYSICAL REVIEW B, 2002, 66 (23) :1-5
[9]   Ionic space-charge effects in polymer light-emitting diodes [J].
deMello, JC ;
Tessler, N ;
Graham, SC ;
Friend, RH .
PHYSICAL REVIEW B, 1998, 57 (20) :12951-12963
[10]   Polymer light-emitting electrochemical cells: Doping, luminescence, and mobility [J].
Edman, L ;
Summers, MA ;
Buratto, SK ;
Heeger, AJ .
PHYSICAL REVIEW B, 2004, 70 (11) :115212-1