Efficient transfer hydrogenation of alkynes and alkenes with methanol catalysed by hydrido(methoxo)iridium(III) complexes

被引：125

作者：

Tani, K ^{[1
]}

Iseki, A ^{[1
]}

Yamagata, T ^{[1
]}

机构：

[1] Osaka Univ, Grad Sch Engn Sci, Dept Chem, Osaka 5608531, Japan

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 18期

关键词：

D O I：

10.1039/a905765j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hydrido(methoxo)iridium(III) complexes, [{Ir(H)(diphosphine)}(2)(mu-OMe)(2)(mu-Cl)]Cl-+(-) [diphosphine = (R)-BINAP 2a or = 2,2'-bis(diphenylphosphino)-1,1'-biphenyl (BPBP) 2b] catalysed transfer hydrogenation of alkynes with methanol to give trans-alkenes selectively; plausible reaction pathways are also proposed.

引用

页码：1821 / 1822

页数：2

共 22 条

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