Dye Regeneration by Spiro-MeOTAD in Solid State Dye-Sensitized Solar Cells Studied by Photoinduced Absorption Spectroscopy and Spectroelectrochemistry

Photoinduced absorption (PIA) spectroscopy is presented as a tool for the systematic study of dye regeneration and pore filling in solid state dye-sensitized solar cells (DSC). Oxidation potentials and extinction coefficients for oxidized species of the perylene dye, ID28, on TiO2 and of the hole conductor, 2,2'7,7'-tetrakis-(N,N-di-p-methoxyphenyl-amine)-9,9'-spirobifluorene (spiro-MeOTAD), were determined by spectroelectrochemistry. The onset of oxidation of a solid film of spiro-MeOTAD was found to be 0.15 V versus Fc/Fc(+) and extinction coefficients of spiro-MeOTAD(+) were found to be 33 000 M-1 cm(-1) at 507 nm and 8500 M-1 cm-' at 690 nm. Electrons in TiO2 films were shown to alter the ground-state absorption spectra of ID28 attached to TiO2-PIA measurements indicated a good contact between ID28 and spiro-MeOTAD for different spiro-MeOTAD concentrations for both 2- and 6-mu m thick TiO2 films. We discuss the possibility of estimating the quality of pore filling from the positions of absorption peaks. Results suggested that with a spiro-MeOTAD concentration of 300 mg mL(-1) in chlorobenzene, a uniform distribution of spiro-MeOTAD in the pores of the 6-mu m thick TiO2 film could be achieved.