Infiltration of precursors into a porous alumina support for ZIF-8 membrane synthesis

被引：46

作者：

Li, Lunxi ^{[1
]}

Yao, Jianfeng ^{[1
]}

Chen, Rizhi ^{[1
]}

He, Li ^{[1
]}

Wang, Kun ^{[1
]}

Wang, Huanting ^{[1
]}

机构：

[1] Monash Univ, Dept Chem Engn, Clayton, Vic 3800, Australia

来源：

MICROPOROUS AND MESOPOROUS MATERIALS | 2013年 / 168卷

基金：

澳大利亚研究理事会;

关键词：

Zeolitic imidazole framework-8; Precursor infiltration; Membrane; Solvothermal synthesis; METAL-ORGANIC FRAMEWORK; MOLECULAR-SIEVE MEMBRANE; SEPARATION; FILMS; SELECTIVITY; MIXTURES;

D O I：

10.1016/j.micromeso.2012.09.029

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A new synthesis method was developed to synthesize ZIF-8 membrane by infiltrating precursors into a porous alumina support as a seed-and-nutrient layer, and subsequent solvothermal synthesis. A precursor layer with a thickness of about 10 mu m was formed inside the porous alumina support and the ZIF-8 membrane grew from both the seeds embedded in the precursor layer and the synthesis solution under solvothermal synthesis conditions. The effects of the solvothermal synthesis temperature and time were investigated, and a continuous and stable ZIF-8 membrane was prepared at 120 degrees C for 8 h. Gas permeation tests indicated the membrane synthesized at 120 degrees C for 8 h was continuous and compact, and had H-2\N-2 ideal selectivity of 5.7 with a H-2 permeance of 1.7 x 10(-7) mol m(-2) s(-1) pa(-1). (C) 2012 Elsevier Inc. All rights reserved.

引用

页码：15 / 18

页数：4

共 34 条

[1] Zeolitic Imidazolate Framework Membrane with Molecular Sieving Properties by Microwave-Assisted Solvothermal Synthesis [J].

Bux, Helge ;

Liang, Fangyi ;

Li, Yanshuo ;

Cravillon, Janosch ;

Wiebcke, Michael ;

Caro, Juergen .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (44) :16000-+

[2] Characterization and permeation properties of ZSM-5 tubular membranes [J].

Coronas, J ;

Falconer, JL ;

Noble, RD .

AICHE JOURNAL, 1997, 43 (07) :1797-1812

[3] Industrial applications of metal-organic frameworks [J].

Czaja, Alexander U. ;

Trukhan, Natalia ;

Mueller, Ulrich .

CHEMICAL SOCIETY REVIEWS, 2009, 38 (05) :1284-1293

[4] HKUST-1 membranes on porous supports using secondary growth [J].

Guerrero, Victor Varela ;

Yoo, Yeonshick ;

McCarthy, Michael C. ;

Jeong, Hae-Kwon .

JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (19) :3938-3943

[5] "Twin Copper Source" Growth of Metal-Organic Framework Membrane: Cu3(BTC)2 with High Permeability and Selectivity for Recycling H2 [J].

Guo, Hailing ;

Zhu, Guangshan ;

Hewitt, Ian J. ;

Qiu, Shilun .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (05) :1646-+

[6] Zeolite a imidazolate frameworks [J].

Hayashi, Hideki ;

Cote, Adrien P. ;

Furukawa, Hiroyasu ;

O'Keeffe, Michael ;

Yaghi, Omar M. .

NATURE MATERIALS, 2007, 6 (07) :501-506

[7] High-flux MFI membranes [J].

Hedlund, J ;

Sterte, J ;

Anthonis, M ;

Bons, AJ ;

Carstensen, B ;

Corcoran, N ;

Cox, D ;

Deckman, H ;

De Gijnst, W ;

de Moor, PP ;

Lai, F ;

McHenry, J ;

Mortier, W ;

Reinoso, J .

MICROPOROUS AND MESOPOROUS MATERIALS, 2002, 52 (03) :179-189

[8] A masking technique for high quality MFI membranes [J].

Hedlund, J ;

Jareman, F ;

Bons, AJ ;

Anthonis, M .

JOURNAL OF MEMBRANE SCIENCE, 2003, 222 (1-2) :163-179

[9] Metal-organic framework membranes fabricated via reactive seeding [J].

Hu, Yaoxin ;

Dong, Xueliang ;

Nan, Jiangpu ;

Jin, Wanqin ;

Ren, Xiaoming ;

Xu, Nanping ;

Lee, Young Moo .

CHEMICAL COMMUNICATIONS, 2011, 47 (02) :737-739

[10] Steam-Stable Zeolitic Imidazolate Framework ZIF-90 Membrane with Hydrogen Selectivity through Covalent Functionalization [J].

Huang, Aisheng ;

Dou, Wei ;

Caro, Juergen .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (44) :15562-15564

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