SO4-ZrO2 catalysts for the esterification of benzoic acid to methylbenzoate

被引:36
作者
Ardizzone, S [1 ]
Bianchi, CL [1 ]
Ragaini, V [1 ]
Vercelli, B [1 ]
机构
[1] Univ Milan, Dept Phys Chem & Electrochem, I-20133 Milan, Italy
关键词
SO4-ZrO2; catalysts; esterification reactions; XPS data;
D O I
10.1023/A:1019026417623
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
SO4-ZrO2 catalysts, prepared by varying the conditions of oxide preparation and H2SO4 impregnation, have been characterized by means of different techniques (XRD, BET, Hammett-Bertolacini technique, XPS). The esterification of benzoic acid to methylbenzoate has been used to test the different catalysts and their catalytic performance has been discussed in the light of their bulk and surface properties.
引用
收藏
页码:59 / 65
页数:7
相关论文
共 36 条
[1]   PREPARATION OF SUPERACIDS BY METAL-OXIDES AND THEIR CATALYTIC ACTION [J].
ARATA, K ;
HINO, M .
MATERIALS CHEMISTRY AND PHYSICS, 1990, 26 (3-4) :213-237
[2]   Preparation of superacids by metal oxides for reactions of butanes and pentanes [J].
Arata, K .
APPLIED CATALYSIS A-GENERAL, 1996, 146 (01) :3-32
[3]   MgO powders: interplay between adsorbed species and localisation of basic sites [J].
Ardizzone, S ;
Bianchi, CL ;
Vercelli, B .
APPLIED SURFACE SCIENCE, 1998, 126 (1-2) :169-175
[4]   Effects of the precursor features and treatments on the catalytic performance of SO4/ZrO2 [J].
Ardizzone, S ;
Bianchi, CL ;
Cattagni, W ;
Ragaini, V .
CATALYSIS LETTERS, 1997, 49 (3-4) :193-198
[5]   A PROCEDURE FOR ACHIEVING SINGLE CRYSTAL-LIKE ZIRCONIA PARTICLES [J].
ARDIZZONE, S ;
BIANCHI, C ;
CARELLA, S ;
CATTANIA, MG .
MATERIALS CHEMISTRY AND PHYSICS, 1993, 34 (02) :154-156
[6]   PREPARATION OF CRYSTALLINE ZIRCONIA POWDERS - CHARACTERIZATION OF THE BULK PHASE AND INTERFACIAL BEHAVIOR [J].
ARDIZZONE, S ;
BASSI, G ;
LIBORIO, G .
COLLOIDS AND SURFACES, 1990, 51 :207-217
[7]   The role of the oxide precursor on the features of sulphated zirconia [J].
Ardizzone, S ;
Bianchi, CL ;
Grassi, E .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 1998, 135 (1-3) :41-51
[8]  
ARDIZZONE S, IN PRESS APPL SURF S
[9]   ACIDITY DISTRIBUTIONS IN CRACKING CATALYSTS [J].
BERTOLACINI, RJ .
ANALYTICAL CHEMISTRY, 1963, 35 (04) :599-&
[10]   The influence of preparation conditions on the surface area of zirconia [J].
Chuah, GK ;
Jaenicke, S ;
Cheong, SA ;
Chan, KS .
APPLIED CATALYSIS A-GENERAL, 1996, 145 (1-2) :267-284