Ship-in-a-bottle synthesis of copper phthalocyanine molecules within mesoporous channels of MCM-41 by a chemical vapor deposition method

被引：39

作者：

Tanamura, Y

Uchida, T

Teramae, N ^{[1
]}

Kikuchi, M

Kusaba, K

Onodera, Y

机构：

[1] Tohoku Univ, Dept Chem, Grad Sch Sci, Aoba Ku, Sendai, Miyagi 9808578, Japan

[2] Tohoku Univ, Mat Res Inst, Aoba Ku, Sendai, Miyagi 9808577, Japan

[3] Natl Inst Adv Ind Sci & Technol, Environm Functional Mat Grp, Inst Environm Management Technol, Miyagino Ku, Sendai, Miyagi 9838551, Japan

来源：

NANO LETTERS | 2001年 / 1卷 / 07期

关键词：

D O I：

10.1021/nl015539p

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report a "ship-in-a-bottle" synthesis where encapsulation of copper phthalocyanines (CuPc) into mesoporous channels of silicate MCM-41 was achieved by chemical vapor deposition (CVD) using 1,2-dicyanobenzene (DCNB). Silanol protons of MCM-41 were ion-exchanged with copper ions before CVD, and when the initial amount of DCNB was much larger than that of copper ions, CuPc molecules in the channels were found to form a cofacial structure that was confirmed by diffuse reflectance spectra.

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页码：387 / 390

页数：4

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