Effect of aqueous phase cloud chemistry on tropospheric ozone

被引：44

作者：

Liang, JY ^{[1
]}

Jacob, DJ ^{[1
]}

机构：

[1] HARVARD UNIV, DEPT EARTH & PLANETARY SCI, CAMBRIDGE, MA 02138 USA

来源：

JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES | 1997年 / 102卷 / D5期

关键词：

D O I：

10.1029/96JD02957

中图分类号：

P4 [大气科学（气象学）];

学科分类号：

0706 ; 070601 ;

摘要：

The sensitivity of tropospheric O-3 to aqueous HOx (OH + HO2) phase chemistry in clouds is examined using photochemical model calculations of the O-3 production efficiency per unit NOx and the chemical lifetime of O-3, combined with estimates for the residence time of air in clouds. It is found that the maximum perturbation to O-3 from cloud chemistry in the tropics and midlatitudes summer is less than 3%. This result is supported by calculations using a three-dimensional, continental-scale model for North America.

引用

页码：5993 / 6001

页数：9

共 50 条

[1] EVALUATED KINETIC AND PHOTOCHEMICAL DATA FOR ATMOSPHERIC CHEMISTRY SUPPLEMENT-IV - IUPAC SUBCOMMITTEE ON GAS KINETIC DATA EVALUATION FOR ATMOSPHERIC CHEMISTRY [J].

ATKINSON, R ;

BAULCH, DL ;

COX, RA ;

HAMPSON, RF ;

KERR, JA ;

TROE, J .

JOURNAL OF PHYSICAL AND CHEMICAL REFERENCE DATA, 1992, 21 (06) :1125-1568

[2]

ATKINSON RA, 1994, J PHYS CHEM REF DATA, V22, P1

[3] TRANSPORT AND RESIDENCE TIMES OF TROPOSPHERIC AEROSOLS INFERRED FROM A GLOBAL 3-DIMENSIONAL SIMULATION OF PB-210 [J].

BALKANSKI, YJ ;

JACOB, DJ ;

GARDNER, GM ;

GRAUSTEIN, WC ;

TUREKIAN, KK .

JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1993, 98 (D11) :20573-20586

[4] NUMERICAL MODELING OF CLOUD AND PRECIPITATION CHEMISTRY ASSOCIATED WITH 2 RAINBANDS AND SOME COMPARISONS WITH OBSERVATIONS [J].

BARTH, MC ;

HEGG, DA ;

HOBBS, PV .

JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1992, 97 (D5) :5825-5845

[5]

CARROLL MA, 1995, ADV PHYSICAL CHEM

[6] NET OZONE PHOTOCHEMICAL PRODUCTION OVER THE EASTERN AND CENTRAL NORTH PACIFIC AS INFERRED FROM GTE CITE-1 OBSERVATIONS DURING FALL 1983 [J].

CHAMEIDES, WL ;

DAVIS, DD ;

RODGERS, MO ;

BRADSHAW, J ;

SANDHOLM, S ;

SACHSE, G ;

HILL, G ;

GREGORY, G ;

RASMUSSEN, R .

JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1987, 92 (D2) :2131-2152

[7] THE FREE-RADICAL CHEMISTRY OF CLOUD DROPLETS AND ITS IMPACT UPON THE COMPOSITION OF RAIN [J].

CHAMEIDES, WL ;

DAVIS, DD .

JOURNAL OF GEOPHYSICAL RESEARCH-OCEANS, 1982, 87 (NC7) :4863-4877

[8] OZONE PRECURSORS AND OZONE PHOTOCHEMISTRY OVER EASTERN NORTH PACIFIC DURING THE SPRING OF 1984 BASED ON THE NASA GTE CITE-1 AIRBORNE OBSERVATIONS [J].

CHAMEIDES, WL ;

DAVIS, DD ;

GREGORY, GL ;

SACHSE, G ;

TORRES, AL .

JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1989, 94 (D7) :9799-9808

[9] OZONE PRECURSOR RELATIONSHIPS IN THE AMBIENT ATMOSPHERE [J].

CHAMEIDES, WL ;

FEHSENFELD, F ;

RODGERS, MO ;

CARDELINO, C ;

MARTINEZ, J ;

PARRISH, D ;

LONNEMAN, W ;

LAWSON, DR ;

RASMUSSEN, RA ;

ZIMMERMAN, P ;

GREENBERG, J ;

MIDDLETON, P ;

WANG, T .

JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1992, 97 (D5) :6037-6055

[10] A global three-dimensional model of tropospheric sulfate [J].

Chin, M ;

Jacob, DJ ;

Gardner, GM ;

ForemanFowler, MS ;

Spiro, PA ;

Savoie, DL .

JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1996, 101 (D13) :18667-18690

← 1 2 3 4 5 →