Bis[bis(2-pyridyl-N) sulfide]palladium(II)bis(tetrafluoroborate)

被引：16

作者：

Nicolo, F

Bruno, G

Tresoldi, G

机构：

[1] Dipto. Chim. Inorg., Analitica S., Univ. degli Studi di Messina, I-98166 Vill. S. Agata, Messina

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 1996年 / 52卷

关键词：

D O I：

10.1107/S010827019600604X

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, [Pd(dps)(2)](BF4)(2) (dps = di-2-pyridyl sulfide, C10H8N2S), has been synthesized by the reaction of dps with the solvated species [Pd(L(2))(acetone)(2)](BF4)2 (L = 1,5-cyclooctadiene) at low temperature. Its structure has been determined by X-ray diffraction. In the [Pd(dps)(2)](2+) cation, the Pd atom lies on a crystallographic inversion centre and exhibits a square-planar geometry involving four pyridine N atoms of both dps molecules acting as chelating ligands [Pd-N1 2.032(2) and Pd-N2 2.026(3) Angstrom]. The two equal six-membered chelate rings are in boat conformations.

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页码：2188 / 2191

页数：4

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