A new ladder-type benzodi(cyclopentadithiophene)-based donor-acceptor polymer and a modified hole-collecting PEDOT: PSS layer to achieve tandem solar cells with an open-circuit voltage of 1.62 V

被引:28
作者
Chen, Yung-Lung [1 ]
Kao, Wei-Shun [1 ]
Tsai, Che-En [1 ]
Lai, Yu-Ying [1 ]
Cheng, Yen-Ju [1 ]
Hsu, Chain-Shu [1 ]
机构
[1] Natl Chiao Tung Univ, Dept Appl Chem, Hsinchu 30010, Taiwan
关键词
CONJUGATED POLYMERS; HIGHLY EFFICIENT; HIGH-PERFORMANCE; ENHANCED EFFICIENCY; RATIONAL DESIGN; INDACENODITHIOPHENE; ARENE;
D O I
10.1039/c3cc43756f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We have developed a new ladder-type conjugated polymer PBDCPDT-FBT and a robust interconnecting layer (ICL) integrating a hole-collecting m-PEDOT:PSS layer with an electron-collecting ZnO layer. The inverted device using PBDCPDT-FBT exhibited a high power conversion efficiency (PCE) of 5.76% with a V-oc of 0.81 V, a J(sc) of 12.82 mA cm(-2), and a FF of 55.5%. The inverted tandem device incorporating the PBDCPDT-FBT and ICL achieves a V-oc of 1.62 V leading to a PCE of 7.08%.
引用
收藏
页码:7702 / 7704
页数:3
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