XPS and SERS evidence for iron nitride species responsible for the strong adhesion of polypyrrole to iron or steel treated with nitric acid

被引：22

作者：

Fraoua, K

Aeiyach, S

Aubard, J

Delamar, M

Lacaze, PC

Ferreira, CA

机构：

[1] Univ Paris 07, Inst Topol & Dynam Syst, CNRS, F-75005 Paris, France

[2] Univ Fed Rio Grande Sul, Escola Engn, Lab Mat Polimer, BR-90035190 Porto Alegre, RS, Brazil

来源：

JOURNAL OF ADHESION SCIENCE AND TECHNOLOGY | 1999年 / 13卷 / 04期

关键词：

XPS; SERS; nitric acid; iron; PPy;

D O I：

10.1163/156856199X00073

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The reason for the strong adhesion of polypyrrole (PPy) films to iron and mild steel surfaces pretreated with dilute nitric acid (HNO3) has been investigated by XPS and SERS techniques. It is shown that iron nitride (Fe Xi N) species, arising from the reaction of HNO3 with the metal, an strongly grafted to the surface. These species could be responsible for the adhesion of PPy films to iron surfaces.

引用

页码：517 / 522

页数：6

共 31 条

[1] ANOMALOUSLY INTENSE RAMAN-SPECTRA OF PYRIDINE AT A SILVER ELECTRODE [J].