Structural information on transition metal(II) complexes of 4,4′-bipyridyl and 4-phenylpyridine from their infrared spectra

被引：13

作者：

Bayari, S ^{[1
]}

Topaçli, A

Salih, B

机构：

[1] Hacettepe Univ, Fac Educ, TR-06532 Ankara, Turkey

[2] Hacettepe Univ, Dept Phys, TR-06532 Ankara, Turkey

[3] Hacettepe Univ, Dept Chem, TR-06532 Ankara, Turkey

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1999年 / 482卷

关键词：

4,4 '-bipyridyl; 4-phenylpyridine; infrared spectroscopy; transition metal complexes;

D O I：

10.1016/S0022-2860(98)00845-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The infrared spectra (4000-300 cm(-1)) are reported for metal(II) chloro 4,4'-bipyridyl and 4-phenylpyridine complexes and metal(II)-isothiocyanate 4-phenylpyridine complexes of the following stoichiometries: [M(bipy)Cl(2)] {M = Mn, Fe, Co or Ni}, [M(4-phpy)(2)Cl(2)] {M = Fe, Co, Cd, Zn, Cu, Hg or Pd} and [M(4-phpy)(n)(NCS)(2)] {n = 2, M = Co, Ni, Zn or Cu; n = 4, M = Fe or Ni} and an assignment is proposed for all the infrared bands. (C) 1999 Elsevier Science B.V. All rights reserved.

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页码：165 / 169

页数：5

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