An experimental proof for negative oxidation states of platinum: ESCA-measurements on barium platinides

被引:31
作者
Karpov, A [1 ]
Konuma, M [1 ]
Jansen, M [1 ]
机构
[1] Max Planck Inst Festkorperforsch, D-70569 Stuttgart, Germany
关键词
D O I
10.1039/b514631c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
ESCA-measurements on barium platinides provide the first spectroscopic evidence for negative oxidation states of platinum and are in excellent agreement with theoretical predictions based on quantum-chemical calculations.
引用
收藏
页码:838 / 840
页数:3
相关论文
共 30 条
[1]   Binding energies in atomic negative ions: III [J].
Andersen, T ;
Haugen, HK ;
Hotop, H .
JOURNAL OF PHYSICAL AND CHEMICAL REFERENCE DATA, 1999, 28 (06) :1511-1533
[2]   Valency and chemical compression of metals in connection with gold [J].
Biltz, W ;
Weibke, F .
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1938, 236 (1/4) :12-23
[3]   MIXED AND PARTIAL OXIDATION STATES - PHOTOELECTRON SPECTROSCOPIC EVIDENCE [J].
CAHEN, D ;
LESTER, JE .
CHEMICAL PHYSICS LETTERS, 1973, 18 (01) :108-111
[4]  
Desclaux J. P., 1974, Atomic Data and Nuclear Data Tables, V12, P311, DOI 10.1016/0092-640X(73)90020-X
[5]   Synthesis and crystal structure determination of tetramethylammonium auride [J].
Dietzel, PDC ;
Jansen, M .
CHEMICAL COMMUNICATIONS, 2001, (21) :2208-2209
[6]  
FELDMANN C, 1993, ANGEW CHEM INT EDIT, V32, P1049, DOI 10.1002/anie.199310491
[7]   GRADUAL ANIONIC CHARACTER OF GOLD IN TERNARY PEROVSKITE-TYPE OXIDES [J].
FELDMANN, C ;
JANSEN, M .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (09) :1045-1046
[8]  
Feldmann C, 1993, ANGEW CHEM, V105, P1107
[9]  
Grant I. P., 1970, Advances in Physics, V19, P747, DOI 10.1080/00018737000101191
[10]   Effects of relativistic motion of electrons on the chemistry of gold and platinum [J].
Jansen, M .
SOLID STATE SCIENCES, 2005, 7 (12) :1464-1474