Solid-state NMR spectroscopy of molecular hydrogen trapped inside an open-cage fullerene

被引：53

作者：

Carravetta, M

Murata, Y

Murata, M

Heinmaa, I

Stern, R

Tontcheva, A

Samoson, A

Rubin, Y

Komatsu, K

Levitt, MH ^{[1
]}

机构：

[1] Univ Southampton, Sch Chem, Southampton, Hants, England

[2] Kyoto Univ, Inst Chem Res, Uji, Kyoto 6110011, Japan

[3] Inst Chem Phys & Biophys, EE-12618 Tallinn, Estonia

[4] Univ Calif Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90095 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 13期

关键词：

D O I：

10.1021/ja031536y

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Solid-state 1H experiments were performed an open-cage fullerene hosting molecular hydrogen. The anisotropy of the molecular hydrogen rotation was studied by double-quantum magic-angle-spinning NMR. The time scale of the molecular hydrogen rotation was estimated by spin-lattice relaxation measurements as a function of temperature. Copyright © 2004 American Chemical Society.

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页码：4092 / 4093

页数：2

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