Effect of operating conditions on tar and gas composition in high temperature air/steam gasification (HTAG) of plastic containing waste

被引:122
作者
Ponzio, A [1 ]
Kalisz, S [1 ]
Blasiak, W [1 ]
机构
[1] Royal Inst Technol KTH, Sch Ind Engn & Management, Dept Mat Sci & Engn, Div Energy & Furnace Technol, SE-10044 Stockholm, Sweden
关键词
gasification; tar; waste; biomass;
D O I
10.1016/j.fuproc.2005.08.002
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
In this work, the high temperature air/steam gasification (HTAG) technique has been tested for a fuel in pellet form made from waste material of woody and plastic origin. The feedstock was gasified in an updraft fixed bed reactor by mixtures of air and steam (102 Nm(3)/h, 4% to 82% steam) preheated to 1400 degrees C, a temperature well above the fluid temperature of the feedstock. The produced gas was analyzed with respect to composition, including a detailed characterization of the tar. Lower heating values up to 9.5 MJ/Nm(3) and gas yields as high as 3.4 Nm(3)/kg were reported, indicating the process to be highly efficient for waste-to-energy applications. The composition of the tars, suggested extensive cracking as a result of the high temperatures of the outgoing gas. (C) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:223 / 233
页数:11
相关论文
共 44 条
[1]  
[Anonymous], 6 INT C SCI THERM CH
[2]   Kinetic and chemical studies of polymer cross-linking using thermal gravimetry and hyphenated methods. Degradation of polyvinylchloride [J].
Anthony, GM .
POLYMER DEGRADATION AND STABILITY, 1999, 64 (03) :353-357
[3]   The continuous self stirred tank reactor:: measurement of the cracking kinetics of biomass pyrolysis vapours [J].
Baumlin, S ;
Broust, F ;
Ferrer, M ;
Meunier, N ;
Marty, E ;
Lédé, J .
CHEMICAL ENGINEERING SCIENCE, 2005, 60 (01) :41-55
[4]  
BLASIAK W, 2002, PYROLYSIS GASIFICATI
[5]   Use of amino phase adsorbent for biomass tar sampling and separation [J].
Brage, C ;
Yu, QZ ;
Chen, GX ;
Sjostrom, K .
FUEL, 1997, 76 (02) :137-142
[6]   Characteristics of evolution of tar from wood pyrolysis in a fixed-bed reactor [J].
Brage, C ;
Yu, QH ;
Sjostrom, K .
FUEL, 1996, 75 (02) :213-219
[7]   Tar evolution profiles obtained from gasification of biomass and coal [J].
Brage, C ;
Yu, QZ ;
Chen, GX ;
Sjöström, K .
BIOMASS & BIOENERGY, 2000, 18 (01) :87-91
[8]   Pyrolysis of virgin and waste polypropylene and its mixtures with waste polyethylene and polystyrene [J].
Ciliz, NK ;
Ekinci, E ;
Snape, CE .
WASTE MANAGEMENT, 2004, 24 (02) :173-181
[9]   Pyrolysis of auto shredder residue: experiments with a laboratory screw kiln reactor [J].
Day, M ;
Shen, Z ;
Cooney, JD .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 1999, 51 (1-2) :181-200
[10]   Pyrolysis of automobile shredder residue: An analysis of the products of a commercial screw kiln process [J].
Day, M ;
Cooney, JD ;
Shen, Z .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 1996, 37 (01) :49-67