Palladium catalysed allylic substitution via in situ activation of allylic alcohols

被引：7

作者：

Kumareswaran, R ^{[1
]}

Vankar, YD ^{[1
]}

机构：

[1] INDIAN INST TECHNOL,DEPT CHEM,KANPUR 208016,UTTAR PRADESH,INDIA

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 48期

关键词：

D O I：

10.1016/S0040-4039(97)10237-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In-situ activation of a variety of allylic alcohols by hexachlorophosphazene (or oxalyl chloride) followed by Pd(0) catalysed reactions with lithio dimethyl malonate leads to the regio and stereoselective alkylations in god yields. (C) 1997 Elsevier Science Ltd.

引用

页码：8421 / 8424

页数：4

共 28 条

[1]

ATKINS KE, 1970, TETRAHEDRON LETT, P3821

[2] HOMOGENEOUS CATALYSIS - PRODUCTION OF ALLYL ALKYL SULFIDES BY PALLADIUM MEDIATED ALLYLATION [J].

AUBURN, PR ;

WHELAN, J ;

BOSNICH, B .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (02) :146-148

[3] ALKYLATION OF ACTIVE METHYLENE-COMPOUNDS BY ALLYLIC ALCOHOLS USING TETRAKIS(TRIPHENYLPHOSPHINE)PALLADIUM(0) CATALYSTS [J].

BERGBREITER, DE ;

WEATHERFORD, DA .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (13) :883-884

[4] POLYETHYLENE-BOUND SOLUBLE RECOVERABLE PALLADIUM(0) CATALYSTS [J].

BERGBREITER, DE ;

WEATHERFORD, DA .

JOURNAL OF ORGANIC CHEMISTRY, 1989, 54 (11) :2726-2730

[5] ISOMERIZATION OF (PI-ALLYL)PALLADIUM COMPLEXES VIA NUCLEOPHILIC DISPLACEMENT BY PALLADIUM(0) - A COMMON MECHANISM IN PALLADIUM(0)-CATALYZED ALLYLIC SUBSTITUTION [J].

GRANBERG, KL ;

BACKVALL, JE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (17) :6858-6863

[6] PALLADIUM-CATALYSED EXCHANGE OF ALLYLIC GROUPS OF ETHERS AND ESTERS WITH ACTIVE-HYDROGEN COMPOUNDS [J].

HATA, G ;

TAKAHASHI, K ;

MIYAKE, A .

JOURNAL OF THE CHEMICAL SOCIETY D-CHEMICAL COMMUNICATIONS, 1970, (21) :1392-+

[7] PALLADIUM(0)-CATALYZED CYCLIZATION OF 2-BUTENYLENE DICARBAMATES FORMING 4-VINYL-2-OXAZOLIDONES [J].

HAYASHI, T ;

YAMAMOTO, A ;

ITO, Y .

TETRAHEDRON LETTERS, 1987, 28 (41) :4837-4840

[8] The (+) and (-) gamma-phenyl-a-methylallyl alcohols. [J].

Kenyon, J ;

Partridge, SM ;

Phillips, H .

JOURNAL OF THE CHEMICAL SOCIETY, 1936, :85-88

[9] PALLADIUM-CATALYZED REACTION OF ALLYL CARBAMATES - ALLYLATION OF CARBONUCLEOPHILES, AND PROTECTION DEPROTECTION OF AMINES [J].

MINAMI, I ;

OHASHI, Y ;

SHIMIZU, I ;

TSUJI, J .

TETRAHEDRON LETTERS, 1985, 26 (20) :2449-2452

[10] REGIOSELECTIVE REMOVAL OF ALLYLIC NITRO-GROUPS VIA HYDRIDE TRANSFER [J].

ONO, N ;

HAMAMOTO, I ;

KAMIMURA, A ;

KAJI, A .

JOURNAL OF ORGANIC CHEMISTRY, 1986, 51 (19) :3734-3736

← 1 2 3 →