Characterisation of the surface of oxidised carbon adsorbents

被引：196

作者：

Strelko, V ^{[1
]}

Malik, DJ ^{[1
]}

Streat, M ^{[1
]}

机构：

[1] Loughborough Univ Technol, Dept Chem Engn, Loughborough LE11 3TU, Leics, England

来源：

CARBON | 2002年 / 40卷 / 01期

关键词：

activated carbon; oxidation; electrophoretic properties; surface oxygen complexes;

D O I：

10.1016/S0008-6223(01)00082-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The surface reactivity and functional group content of a series of oxidised active carbons has been assessed by elemental analysis, electrophoretic mobility measurements and potentiometric titrations. Oxidation of carbons with hot air resulted in a greater proportion of relatively weak acidic surface functional groups (i.e., phenolic), whereas nitric acid modification produced a greater amount of carboxylic groups. Electrophoretic mobility measurements suggest that the carbon surface is negatively charged within the range of the pH values studied. pH titration results indicate that the surface acidity of active carbons is stronger than that of a commercial polymeric carboxylic acid ion exchange resin. Possible mechanisms of carbon surface oxidation are discussed. (C) 2002 Published by Elsevier Science Ltd.

引用

页码：95 / 104

页数：10

共 34 条

[1] CHARACTERIZATION OF THE SURFACES OF ACTIVATED CARBONS IN TERMS OF THEIR ACIDITY CONSTANT DISTRIBUTIONS [J].

BANDOSZ, TJ ;

JAGIELLO, J ;

CONTESCU, C ;

SCHWARZ, JA .

CARBON, 1993, 31 (07) :1193-1202

[2] INFLUENCE OF THE OXYGEN-SURFACE COMPLEXES OF ACTIVATED CARBONS ON THE ADSORPTION OF CHROMIUM IONS FROM AQUEOUS-SOLUTIONS - EFFECT OF SODIUM-CHLORIDE AND HUMIC-ACID [J].

BAUTISTATOLEDO, I ;

RIVERAUTRILLA, J ;

FERROGARCIA, MA ;

MORENOCASTILLA, C .

CARBON, 1994, 32 (01) :93-100

[3]

Boehm H.P., 1966, CHEM IDENTIFICATION, V16,, P179, DOI [10.1016/S0360-0564(08)60354-5, DOI 10.1016/S0360-0564(08)60354-5]

[4] SOME ASPECTS OF THE SURFACE-CHEMISTRY OF CARBON-BLACKS AND OTHER CARBONS [J].

BOEHM, HP .

CARBON, 1994, 32 (05) :759-769

[5] THE SURFACE-ACIDITY AND CHARACTERIZATION OF SOME COMMERCIAL ACTIVATED CARBONS [J].

CORAPCIOGLU, MO ;

HUANG, CP .

CARBON, 1987, 25 (04) :569-578

[6] CHEMICAL REACTIVITY OF CARBONS [J].

DONNET, JB .

CARBON, 1968, 6 (02) :161-&

[7] CARBON-FIBER IN POLYMER REINFORCEMENT [J].

DONNET, JB ;

EHRBURGER, P .

CARBON, 1977, 15 (03) :143-152

[8] ADSORPTION OF ZINC, CADMIUM, AND COPPER ON ACTIVATED CARBONS OBTAINED FROM AGRICULTURAL BY-PRODUCTS [J].

FERROGARCIA, MA ;

RIVERAUTRILLA, J ;

RODRIGUEZGORDILLO, J ;

BAUTISTATOLEDO, I .

CARBON, 1988, 26 (03) :363-373

[9]

Garten V.A, 1957, REV PURE APPL CHEM, V7, P69

[10]

HELFFERICH F, 1995, ION EXCHANGE, P92

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