The Cl2(PCy3)(IMes)Ru(=CHPh) catalyst:: olefin metathesis versus olefin isomerization

被引：129

作者：

Bourgeois, D

Pancrazi, A

Nolan, SP ^{[1
]}

Prunet, J

机构：

[1] Univ New Orleans, Dept Chem, New Orleans, LA 70148 USA

[2] UCP, ESCOM, Synth Organ Lab, F-95092 Cergy Pontoise, France

[3] Ecole Polytech, DCSO, CNRS, Lab Synth Organ, F-91128 Palaiseau, France

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2002年 / 643卷

关键词：

ruthenium; carbene; metathesis; isomerization;

D O I：

10.1016/S0022-328X(01)01269-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

While investigating RCM of substrates requiring elevated temperatures and extended reaction times, significant isomerization of one of the double bonds in the starting diene was observed with the recently developed [RuIMes] catalyst. This isomerization appeared as an important drawback of the catalyst, but a judicious selection of solvent and additive can completely eliminate this side reaction. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：247 / 252

页数：6

共 27 条

[1] Ruthenium carbene complexes with imidazolin-2-ylidene ligands allow the formation of tetrasubstituted cycloalkenes by RCM [J].