Synthesis of a new magnetic Y2Mn2/3Re4/3O7 with pyrochlore-like structure

被引:5
作者
Bazuev, GV [1 ]
Chupakhina, TI [1 ]
Krasil'nikov, VN [1 ]
机构
[1] Russian Acad Sci, Inst Solid State Chem, Ural Div, Ekaterinburg 620219, Russia
关键词
D O I
10.1134/1.1427131
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
A complex oxide of the Y2Mn2/3Re4/3O7 composition with pyrochlore-like structure and parameters of hexagonal unit cell a = 14.91(1) Angstrom, c = 17.53(1) Angstrom was synthesized. The magnetic susceptibility and magnetization measurements showed that below 190 K this oxide possesses spontaneous magnetic moment. In the paramegnetic region, the magnetic susceptibility obeys the Curie-Weiss law chi = C/(T - Theta), with C = 2.07 cm(3) K mol(-1) and Theta = -160 K, and the effective magnetic moment corresponding to the cationic combination Mn2+-Re5+. The data obtained allow one to assume that the compound has a noncollinear antiferromagnetic structure. (C) 2001 MAIK "Nauka /Interperiodica".
引用
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页码:401 / 403
页数:3
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