A facile and general method for the synthesis of 6,12-diaryl-5,11-dihydroindolo[3,2-b]carbazoles

被引:46
作者
Gu, Rong [1 ]
Van Snick, Sven [1 ]
Robeyns, Koen [1 ]
Van Meervelt, Luc [1 ]
Dehaen, Wim [1 ]
机构
[1] Katholieke Univ Leuven, Dept Chem, B-3001 Louvain, Belgium
关键词
THIN-FILM TRANSISTORS; HOLE-TRANSPORTING MATERIALS; LIGHT-EMITTING-DIODES; ONE-POT SYNTHESIS; CONDUCTIVE PROPERTIES; MOLECULAR-IODINE; HIGH-MOBILITY; DERIVATIVES;
D O I
10.1039/b815908d
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A facile and general two-step method towards 6,12-diaryl-5,11-dihydroindolo[3,2-b] carbazoles has been developed. Hydroiodic acid was an efficient catalyst for the condensation of indole and aromatic aldehydes, and iodine was used as an oxidation reagent to afford symmetrical 6,12-diaryl-5,11-dihydroindolo[3,2-b] carbazoles in moderate to good overall yields.
引用
收藏
页码:380 / 385
页数:6
相关论文
共 20 条
[1]  
[Anonymous], 1997, S HELXS 97 SHELXL 97
[2]  
ASARI T, 2006, Patent No. 2006098229
[3]   Optical, electrochemical, magnetic, and conductive properties of new poly (indolocarbazole-alt-bithiophene)s [J].
Blouin, N ;
Leclerc, M ;
Vercelli, B ;
Zecchin, S ;
Zotti, G .
MACROMOLECULAR CHEMISTRY AND PHYSICS, 2006, 207 (02) :175-182
[4]   Optical, electrochemical, magnetic, and conductive properties of new polyindolocarbazoles and polydiindolocarbazoles [J].
Blouin, N ;
Michaud, A ;
Wakim, S ;
Boudreault, PLT ;
Leclerc, M ;
Vercelli, B ;
Zecchin, S ;
Zotti, G .
MACROMOLECULAR CHEMISTRY AND PHYSICS, 2006, 207 (02) :166-174
[5]  
*BRUK AXS INC, 1997, SADABS VERS 2 10 SAI
[6]   An efficient method for the synthesis of indolo[3,2-b]carbazoles from 3,3′-bis(indolyl)methanes catalyzed by molecular iodine [J].
Deb, Mohit L. ;
Bhuyan, Pulak J. .
SYNLETT, 2008, (03) :325-328
[7]   A facile synthesis of 6,12-disubstituted 5,7-dihydroindolo[2,3-b]carbazoles from the reaction of 1H-Indole and aldehydes catalyzed by molecular iodine [J].
Deb, Mohit L. ;
Baruah, Biswajita ;
Bhuyan, Pulak J. .
SYNTHESIS-STUTTGART, 2008, (02) :286-292
[8]   Facile one-pot synthesis of novel 6-monosubstituted 5,11-dihydroindolo[3,2-b]carbazoles and preparation of different derivatives [J].
Gu, Ron ;
Hameurlaine, Ahmed ;
Dehaen, Wim .
SYNLETT, 2006, (10) :1535-1538
[9]   Facile one-pot synthesis of 6-monosubstituted and 6,12-disubstituted 5,11-dihydroindolo[3,2-b]carbazoles and preparation of various functionalized derivatives [J].
Gu, Rong ;
Hameurlaine, Ahmed ;
Dehaen, Wim .
JOURNAL OF ORGANIC CHEMISTRY, 2007, 72 (19) :7207-7213
[10]   Oxidative reactions of 6-pentyl indolo[3,2-b]carbazole:: formation of novel C-C and C-N coupled dimers [J].
Gu, Rong ;
Van Hecke, Kristof ;
Van Meervelt, Luc ;
Toppet, Suzanne ;
Dehaen, Wim .
ORGANIC & BIOMOLECULAR CHEMISTRY, 2006, 4 (20) :3785-3789