Rational design and HT techniques allow the synthesis of new IWR zeolite polymorphs

被引：74

作者：

Cantín, A ^{[1
]}

Corma, A ^{[1
]}

Diaz-Cabanas, MJ ^{[1
]}

Jordá, JL ^{[1
]}

Moliner, M ^{[1
]}

机构：

[1] Univ Politecn Valencia, Inst Tecnol Quim, CSIC, Valencia 46022, Spain

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 13期

关键词：

D O I：

10.1021/ja0603599

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

By combining a rational design of structure directing agents and high throughput and data mining techniques, it has been possible to obtain Ge-free ITQ-24 as pure silica as well as borosilicate polymorphs up to a Si/TIII ratio of 10. Al can be exchanged by B giving strong acid materials. Also, the availability of the pure silica material allows one to determine more precisely the crystal symmetry. This work opens the possibility to synthesize the Ge-free polymorphs of a large number of new germanosilicate structures reported in the last five years. This certainly will increase their possibilities for industrial application. Copyright © 2006 American Chemical Society.

引用

页码：4216 / 4217

页数：2

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