Striped domains at the pentacene:C60 interface

被引:25
作者
Dougherty, Daniel B. [1 ]
Jin, Wei [2 ,3 ]
Cullen, William G. [3 ,4 ]
Reutt-Robey, Janice E. [2 ,3 ]
Robey, Steven W. [1 ]
机构
[1] Natl Inst Stand & Technol, Gaithersburg, MD 20899 USA
[2] Univ Maryland, Dept Chem & Biochem, College Pk, MD 20742 USA
[3] Univ Maryland, Mat Res Sci & Engn Ctr, College Pk, MD 20742 USA
[4] Univ Maryland, Dept Phys, College Pk, MD 20742 USA
基金
美国国家科学基金会;
关键词
carbon; monolayers; organic semiconductors; scanning tunnelling microscopy; semiconductor thin films; silver; SCANNING TUNNELING MICROSCOPE; SOLAR-CELLS; MONOLAYER; SURFACES; AU(111); ENERGY; DIPOLE; IMAGE;
D O I
10.1063/1.3046721
中图分类号
O59 [应用物理学];
学科分类号
摘要
Scanning tunneling microscopy observations of the initial growth stages of the first layer of pentacene on a monolayer film of C-60 on Ag(111) are presented. Pentacene films nucleate and grow with molecules standing up at the pentacene:C-60 interface similar to thin film phases observed on weakly interacting substrates such as SiO2. Unlike reported thin film pentacene phases, those on 1 monolayer C-60/Ag(111) exhibit a striated morphology with domains of 4 nm nominal width. This long range pattern of periodic pentacene displacements relative to the substrate is the response to stress induced in the pentacene film by its interaction with the rigid C-60 support.
引用
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页数:3
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