A novel tridentate NHC-Pd(II) complex and its application in the Suzuki and Heck-type cross-coupling reactions

被引：81

作者：

Chen, Tao

Gao, Jun

Shi, Min

机构：

[1] E China Univ Sci & Technol, Sch Chem & Mol Engn, Shanghai 200237, Peoples R China

[2] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, Shanghai 200032, Peoples R China

来源：

TETRAHEDRON | 2006年 / 62卷 / 26期

基金：

中国国家自然科学基金;

关键词：

tridentate NHC-Pd(II) complex; binaphthyl-2,2 '-diamine; cross-coupling reactions; Suzuki-Miyaura cross-coupling reaction; Heck reaction;

D O I：

10.1016/j.tet.2006.04.034

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel tridentate NHC-Pd(II) complex derived from binaphthyl-2,2'-diamine (BINAM) has been synthesized and its structure has been characterized by single crystal X-ray diffraction. This NHC-Pd(II) complex was fairly effective in Suzuki and Heck-type cross-coupling reactions to give the products in good to excellent yields in most cases. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：6289 / 6294

页数：6

共 19 条

[1] On C-C coupling by carbene-stabilized palladium catalysts: A density functional study of the Heck reaction [J].