Enzyme-catalyzed regioselective synthesis of sugar esters and related compounds

被引：106

作者：

Kennedy, John F.

Kumar, Harish

Panesar, Parmjit S.

Marwaha, Satwinder S.

Goyal, Rita

Parmar, Anupama

Kaur, Sukhwinder

机构：

[1] Univ Birmingham, Chembiotech Labs, Birmingham B15 2SQ, W Midlands, England

[2] Univ Birmingham, Sch Chem, Birmingham Carbohydrate & Prot Technol Grp, Birmingham B15 2TT, W Midlands, England

[3] Sant Longowal Inst Engn & Technol, Dept Chem, Longowal 148106, India

[4] Sant Longowal Inst Engn & Technol, Dept Food Technol, Longowal 148106, India

[5] Punjab State Council Sci & Technol, Chandigarh 160022, India

来源：

JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY | 2006年 / 81卷 / 06期

关键词：

enzymatic; lipases; esterification; regioselective; sugars; monosaccharide; disaccharide; ionic liquids; fatty acids; esters; microwaves;

D O I：

10.1002/jctb.1473

中图分类号：

Q81 [生物工程学（生物技术）]; Q93 [微生物学];

学科分类号：

071005 [微生物学]; 0836 [生物工程]; 090102 [作物遗传育种]; 100705 [微生物与生化药学];

摘要：

In this review, a comprehensive and illustrative survey is made of the regioselective synthesis of esters of sugars and related compounds using lipases. The main emphasis has been given to the screening and use of commercially available lipases for the enzymatic esterification of neutral monosaccharides, disaccharides, sugar alcohols and their selected ether and ester derivatives. The effect of solvents and solubilizing agents in improving the yields of the resultant sugar fatty acid esters has been incorporated. Further, solvent-free esterification with molten fatty acids, use of ionic liquids and microwave radiations for improvement in the methodology have also been discussed. (c) 2006 Society of Chemical Industry.

引用

页码：866 / 876

页数：11

共 90 条

[1]

ADAMS WF, 1985, ERNULGATOREN LEBENSM

[2]

ENZYME CATALYZED PREPARATION OF 6-O-ACYLGLUCOPYRANOSIDES [J].