8,16,24,32-tetramethoxy[2.2.2.2]metacyclophane-1,9,17,25-tetrayne: A novel ionophore having a preorganized but unexpectedly flexible cavity

被引：21

作者：

Kawase, T ^{[1
]}

Hosokawa, Y ^{[1
]}

Kurata, H ^{[1
]}

Oda, M ^{[1
]}

机构：

[1] Osaka Univ, Grad Sch Sci, Dept Chem, Toyonaka, Osaka 5600043, Japan

来源：

CHEMISTRY LETTERS | 1999年 / 08期

关键词：

D O I：

10.1246/cl.1999.745

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title cyclophane has a preorganized cavity with about 1.2 Angstrom in diameter surrounded by four oxygen atoms (X-ray analysis); however, solvent extraction experiments using alkali metal picrates revealed the unexpectedly flexible nature of the cavity that forms 1:1 complexes with various alkali metal ions with considerably large association constants.

引用

页码：745 / 746

页数：2

共 20 条

[1] AUGMENTED AND DIMINISHED SPHERANDS AND SCALES OF BINDING [J].

CRAM, DJ ;

LEIN, GM ;

KANEDA, T ;

HELGESON, RC ;

KNOBLER, CB ;

MAVERICK, E ;

TRUEBLOOD, KN .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (20) :6228-6232

[2] PREORGANIZATION - FROM SOLVENTS TO SPHERANDS [J].

CRAM, DJ .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1986, 25 (12) :1039-1057

[3] HYDROGEN-BOND STUDIES .120. X-RAY DETERMINATION OF CRYSTAL-STRUCTURE OF LINO3.3H2O [J].

HERMANSSON, K ;

THOMAS, JO ;

OLOVSSON, I .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1977, 33 (SEP15) :2857-2861

[4]

Hoger S, 1995, ANGEW CHEM INT EDIT, V34, P2713

[5] Novel cavity design using calix[n]arene skeletons: Toward molecular recognition and metal binding [J].

Ikeda, A ;

Shinkai, S .

CHEMICAL REVIEWS, 1997, 97 (05) :1713-1734

[6] THERMODYNAMIC AND KINETIC DATA FOR MACROCYCLE INTERACTION WITH CATIONS AND ANIONS [J].

IZATT, RM ;

PAWLAK, K ;

BRADSHAW, JS ;

BRUENING, RL .

CHEMICAL REVIEWS, 1991, 91 (08) :1721-2085

[7] A SPHERAND AZOPHENOL DYE - LITHIUM ION SPECIFIC COLORATION WITH PERFECT SELECTIVITY [J].

KANEDA, T ;

UMEDA, S ;

TANIGAWA, H ;

MISUMI, S ;

KAI, Y ;

MORII, H ;

MIKI, K ;

KASAI, N .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (16) :4802-4803

[8] [2.2.2.2]metacyclophane-1,9,17,25-tetrayne [J].

Kawase, T ;

Ueda, N ;

Darabi, HR ;

Oda, M .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (13-14) :1556-1558

[9] [2.2.2]metacyclophane-1,9,17-triyne [J].

Kawase, T ;

Ueda, N ;

Oda, M .

TETRAHEDRON LETTERS, 1997, 38 (38) :6681-6684

[10] EXTRACTION OF ALKALI-METAL PICRATES WITH POLY(CROWN ETHER) AND BIS(CROWN ETHER) [J].

KIMURA, K ;

MAEDA, T ;

SHONO, T .

TALANTA, 1979, 26 (10) :945-949

← 1 2 →