Direct observation of the oceanic CO2 increase revisited

被引:37
作者
Brewer, PG [1 ]
Goyet, C [1 ]
Friederich, G [1 ]
机构
[1] WOODS HOLE OCEANOG INST,WOODS HOLE,MA 02543
关键词
D O I
10.1073/pnas.94.16.8308
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
We show, from recent data obtained at specimen North Pacific stations, that the fossil fuel CO2 signal is strongly present in the upper 400 m, and that we may consider areal extrapolations from geochemical surveys to determine the magnitude of ocean fossil fuel CO2 uptake. The debate surrounding this topic is illustrated by contrasting reports which suggest, based upon atmospheric observations and models, that the oceanic CO2 sink is small at these latitudes; or that the oceanic CO2 sink, based upon oceanic data and models, is large, The difference between these two estimates is at least a factor of two, There are contradictions arising from estimates based on surface partial pressures of CO2 alone, where the signal sought is small compared with regional and seasonal variability; and estimates of the accumulated subsurface burden, which correlates well other oceanic tracers, Ocean surface waters today contain about 45 mu mol.kg(-1) excess CO2 compared with those of the preindustrial era, and the signal is rising rapidly, What limits should we place on such calculations? The answer lies in the scientific questions to be asked, Recovery of the fossil fuel CO2 contamination signal from analysis of ocean water masses is robust enough to permit reasonable budget estimates, However, because we do not have sufficient data from the preindustrial ocean, the estimation of the required Redfield oxidation ratio in the upper several hundred meters is already blurred by the very fossil fuel CO2 signal we seek to resolve.
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页码:8308 / 8313
页数:6
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