Monolayer films of poly(dimethylsiloxane) on aqueous surfactant solutions

被引:23
作者
Bergeron, V [1 ]
Langevin, D [1 ]
机构
[1] CNRS,CTR RECH PAUL PASCAL,F-33600 PESSAC,FRANCE
关键词
D O I
10.1021/ma950325d
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Spreading at the air-solution interface, of poly(dimethylsiloxane) (PDMS), a widely used ingredient in commercial antifoaming agents, depends strongly on the type of surfactant dissolved in solution. To isolate which polymer-surfactant interactions control the process, we measure surface pressure isotherms for PDMS on a wide variety of surfactant solutions. Moreover, we directly probe the influence of electrostatic forces by addition of a 1:1 electrolyte to the solutions. Although surfactant type, anionic, cationic, or nonionic, and level of charge play only a minor role, the length of the surfactant tail can control the PDMS spreading behavior. For the homologous series of alkyltrimethylammonium bromides, a critical carbon chain length of 14 is found, above which PDMS displays ''complete'' wetting behavior. However, shorter chain lengths can induce a metastable condition of ''pseudopartial'' wetting. We utilize both two dimensional polymer scaling concepts and generalized spreading coefficients to rationalize our results.
引用
收藏
页码:306 / 312
页数:7
相关论文
共 35 条
[1]  
ADAMSON AW, 1976, PHYSICAL CHEM SURFAC
[2]  
[Anonymous], SURFACTANT SCI SERIE
[3]  
BANKS WH, 1957, GAS LIQUID LIQUID LI, P16
[4]   GENERALIZED ENTERING COEFFICIENTS - A CRITERION FOR FOAM STABILITY AGAINST OIL IN POROUS-MEDIA [J].
BERGERON, V ;
FAGAN, ME ;
RADKE, CJ .
LANGMUIR, 1993, 9 (07) :1704-1713
[5]  
BERGERON V, UNPUB PHYS REV LETT
[6]  
BERGERON V, 1993, THESIS U CALIFORNIA
[7]   SPREADING OF NONVOLATILE LIQUIDS IN A CONTINUUM PICTURE [J].
BROCHARDWYART, F ;
DIMEGLIO, JM ;
QUERE, D ;
DEGENNES, PG .
LANGMUIR, 1991, 7 (02) :335-338
[8]   SPREADING AT THE MICROSCOPIC SCALE [J].
CAZABAT, AM ;
FRAYSSE, N ;
HESLOT, F ;
CARLES, P .
JOURNAL OF PHYSICAL CHEMISTRY, 1990, 94 (19) :7581-7585
[9]   THE SHAPE OF THE TRANSITION ZONE BETWEEN A THIN-FILM AND BULK LIQUID AND THE LINE TENSION [J].
CHURAEV, NV ;
STAROV, VM ;
DERJAGUIN, BV .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1982, 89 (01) :16-24
[10]   WETTING FILMS AND WETTING [J].
CHURAEV, NV .
REVUE DE PHYSIQUE APPLIQUEE, 1988, 23 (06) :975-987