Stochastic Resonance in a Molecular Redox Circuit

被引:29
作者
Hirano, Yoshiaki [1 ]
Segawa, Yuji [2 ]
Kawai, Tomoji [2 ]
Matsumoto, Takuya [1 ]
机构
[1] Osaka Univ, Sch Sci, Dept Chem, Toyonaka, Osaka 5600043, Japan
[2] Osaka Univ, ISIR, Ibaraki, Osaka 5670047, Japan
关键词
TRANSPORT; SYSTEMS; DEVICES; NOISE;
D O I
10.1021/jp310486z
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Beyond single molecule electronics, exploration of device architecture is a central issue in molecular-scale electronics. We have demonstrated that the cytochrome c (Cyt c) network array acts as an electronic circuit that consists of a redox element. The current voltage characteristics of the Cyt c network array reveal nonlinear curves with a threshold voltage (V-th) that corresponds well with the Coulomb blockade (CB) model over a wide range of temperature. As an indication of the threshold behavior, a weak periodic input signal is optimized by the presence of a particular level of noise that enhances signal detection. This result indicates that stochastic resonance (SR) emerges in the Cyt c redox network array.
引用
收藏
页码:140 / 145
页数:6
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