Carbon dioxide utilization as a soft oxidant and promoter in catalysis

被引：235

作者：

Ansari, Mohd Bismillah ^{[1
]}

Park, Sang-Eon

机构：

[1] Inha Univ, Dept Chem, Lab Nano Green Catalysis, Inchon 402751, South Korea

来源：

ENERGY & ENVIRONMENTAL SCIENCE | 2012年 / 5卷 / 11期

基金：

新加坡国家研究基金会;

关键词：

OXIDATIVE DEHYDROGENATION; C-2; HYDROCARBONS; ETHYLBENZENE DEHYDROGENATION; SELECTIVE CONVERSION; UTILIZING CO2; N-BUTANE; NA2WO4-MN/SIO2; CATALYST; AROMATIC-ALDEHYDES; HIGH-PERFORMANCE; PHASE OXIDATION;

D O I：

10.1039/c2ee22409g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The utilization of CO2 as a soft oxidant and promoter is a promising concept for industrial applications that could not only contribute to the mitigation of CO2 levels, but also the development of economical and energy efficient syntheses of various chemicals. The abundant availability, non-toxic, economic and mild oxidizing properties of CO2 has resulted in immense interest in its use as an oxidant in several reactions, such as the oxidative coupling of CH4 and the oxidative dehydrogenation of alkanes and alkyl aromatics. At present, only a few processes based on CO2 as a soft oxidant have been realised on a technical scale in spite of dedicated research. This review is intended to trace the emergence, application and understanding of such systems and shed light on the further development that may lead to industrial scale operations in the near future.

引用

页码：9419 / 9437

页数：19

共 146 条

[1] CATALYTIC OXIDATIONS WITH SULFUR DIOXIDE .2. ALKYLAROMATICS [J].

ADAMS, CR ;

JENNINGS, TJ .

JOURNAL OF CATALYSIS, 1970, 17 (02) :157-&

[2] CO2 activation and promotional effect in the oxidation of cyclic olefins over mesoporous carbon nitrides [J].

Ansari, Mohd Bismillah ;

Min, Byung-Hoon ;

Mo, Yong-Hwan ;

Park, Sang-Eon .

GREEN CHEMISTRY, 2011, 13 (06) :1416-1421

[3] Mechanism of formation of peroxocarbonates RhOOC(O)O(Cl)(P)(3) and their reactivity as oxygen transfer agents mimicking monooxygenases. The first evidence of CO2 insertion into the O-O bond of Rh(eta(2)-O-2) complexes [J].

Aresta, M ;

Tommasi, I ;

Quaranta, E ;

Fragale, C ;

Mascetti, J ;

Tranquille, M ;

Galan, F ;

Fouassier, M .

INORGANIC CHEMISTRY, 1996, 35 (14) :4254-4260

[4] CARBON-DIOXIDE AS MODULATOR OF THE OXIDATIVE PROPERTIES OF DIOXYGEN IN THE PRESENCE OF TRANSITION-METAL SYSTEMS [J].

ARESTA, M ;

FRAGALE, C ;

QUARANTA, E ;

TOMMASI, I .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (04) :315-317

[5] Synthesis of ethane and ethylene from methane and carbon dioxide over praseodymium oxide catalysts [J].

Asami, K ;

Kusakabe, K ;

Ashi, N ;

Ohtsuka, Y .

APPLIED CATALYSIS A-GENERAL, 1997, 156 (01) :43-56

[6] CONVERSION OF METHANE WITH CARBON-DIOXIDE INTO C-2 HYDROCARBONS OVER METAL-OXIDES [J].

ASAMI, K ;

FUJITA, T ;

KUSAKABE, K ;

NISHIYAMA, Y ;

OHTSUKA, Y .

APPLIED CATALYSIS A-GENERAL, 1995, 126 (02) :245-255

[7] Oxidative dehydrogenation of ethylbenzene with carbon dioxide on alkali-promoted Fe active carbon catalysts [J].

Badstube, T ;

Papp, H ;

Kustrowski, P ;

Dziembaj, R .

CATALYSIS LETTERS, 1998, 55 (3-4) :169-172

[8] Selective Conversion of Ethane to Ethene via Oxidative Dehydrogenation Over Ca-doped ThO2 Using CO2 as Oxidant [J].

Baidya, Tinku ;

van Vegten, Niels ;

Baiker, Alfons .

TOPICS IN CATALYSIS, 2011, 54 (13-15) :881-887

[9]

BARTHOLOMEW CH, 1984, CHEM ENG-NEW YORK, V91, P96

[10] Use of carbon dioxide in chemical syntheses via a lactone intermediate [J].

Behr, A. ;

Henze, G. .

GREEN CHEMISTRY, 2011, 13 (01) :25-39

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