Reactions of α-chloro β-oxo aldehydes with CH-acid anions

被引：2

作者：

Guseinov, FI ^{[1
]}

机构：

[1] Kazan State Technol Univ, Kazan 420015, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 1999年 / 48卷 / 04期

关键词：

alpha-chloro beta-oxo aldehydes; carbanions; CH-acids;

D O I：

10.1007/BF02496260

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reactions of alpha-chloro and alpha,alpha-dichloro beta-oxo aldehydes with carbanions are accompanied by the cleavage of the carbon-carbon bond in the chloro aldehydes and result in formylation of CH-acids. These electrophiles react with carbanions, which are generated in situ from CH-acids in the presence of AcONa in aprotic solvents, to form polyfunctional hydroxy compounds.

引用

页码：743 / 745

页数：3

共 12 条

[1]

[Anonymous], 1984, SVOISTVA ORGANICHESK

[2]

GUSEINOV FI, 1994, ZH ORG KHIM+, V30, P360

[3]

GUSEINOV FI, 1995, ZH ORG KHIM+, V31, P96

[4]

Guseinov FI, 1997, ZH OBSHCH KHIM+, V67, P1663