Novel thermosets prepared by cationic copolymerization of various vegetable oils - synthesis and their structure-property relationships

被引：134

作者：

Andjelkovic, DD ^{[1
]}

Valverde, M ^{[1
]}

Henna, P ^{[1
]}

Li, FK ^{[1
]}

Larock, RC ^{[1
]}

机构：

[1] Iowa State Univ Sci & Technol, Dept Chem, Ames, IA 50011 USA

来源：

POLYMER | 2005年 / 46卷 / 23期

关键词：

vegetable oil; cationic copolymerization; structure-property relationship;

D O I：

10.1016/j.polymer.2005.08.022

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A range of thermoset plastics have been prepared by the cationic copolymerization of olive, peanut, sesame, canola, corn, soybean, grapeseed, sunflower, low saturation soy, safflower, walnut, and linseed oils with divinylbenzene or a combination of styrene and divinylbenzene comonomers catalyzed by boron trifluoride diethyl etherate. The chemical, physical, thermal, and mechanical properties of these new polymers have been investigated as a function of the vegetable oil composition. The vegetable oil reactivity has a direct effect on most of the polymers' properties, which can be reasonably predicted by careful choice of the vegetable oil. Coupled with variations in the comonomer and stoichiometry, the choice of vegetable oil allows one to tailor the polymer's properties for specific applications. (c) 2005 Elsevier Ltd. All rights reserved.

引用

页码：9674 / 9685

页数：12

共 42 条

[1] Rigid thermosetting liquid molding resins from renewable resources.: II.: Copolymers of soybean oil monoglyceride maleates with neopentyl glycol and bisphenol A maleates
Can, E
Küsefoglu, S
Wool, RP
[J]. JOURNAL OF APPLIED POLYMER SCIENCE, 2002, 83 (05) : 972 - 980
[2] Rigid, thermosetting liquid molding resins from renewable resources.: I.: Synthesis and polymerization of soy oil monoglyceride maleates
Can, E
Küsefoglu, S
Wool, RP
[J]. JOURNAL OF APPLIED POLYMER SCIENCE, 2001, 81 (01) : 69 - 77
[3] ECKEY EW, 1954, ACS MONOGRAPHS SERIE
[4] FLORY PJ, 1953, PRINCIPLES POLYM CHE, pCH6
[5] Rapid simultaneous determination by proton NMR of unsaturation and composition of acyl groups in vegetable oils
Guillén, MD
Ruiz, A
[J]. EUROPEAN JOURNAL OF LIPID SCIENCE AND TECHNOLOGY, 2003, 105 (11) : 688 - 696
[6] Guo A, 2000, J APPL POLYM SCI, V77, P467, DOI 10.1002/(SICI)1097-4628(20000711)77:2<467::AID-APP25>3.3.CO
[7] 2-6
[8] Polyols and polyurethanes from hydroformylation of soybean oil
Guo, A
Demydov, D
Zhang, W
Petrovic, ZS
[J]. JOURNAL OF POLYMERS AND THE ENVIRONMENT, 2002, 10 (1-2) : 49 - 52
[9] Javni I, 2000, J APPL POLYM SCI, V77, P1723, DOI 10.1002/1097-4628(20000822)77:8<1723::AID-APP9>3.0.CO
[10] 2-K

← 1 2 3 4 5 →