Intermolecular bond length of ice on Ag(111)

被引：105

作者：

Morgenstern, K

Nieminen, J

机构：

[1] Free Univ Berlin, Fachbereich Phys, Inst Expt Phys, D-14195 Berlin, Germany

[2] Tampere Univ Technol, Inst Phys, FIN-33101 Tampere, Finland

来源：

PHYSICAL REVIEW LETTERS | 2002年 / 88卷 / 06期

关键词：

D O I：

10.1103/PhysRevLett.88.066102

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

Water adsorbed in submonolayer coverage on Ag(111) at 70 K forms hydrogen-bonded networks. High resolution images in combination with calculation reveal that single protrusions represent a cyclic water hexamer with the intermolecular bond stretched to the silver lattice constant of 0.29 nm. Scanning tunneling spectroscopy indicates that the bond length within the two-dimensional hydrogen-bonded water layer is shortened. The spectra contain further information about the vibrational modes of water molecules.

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页码：66102/1 / 66102/4

页数：4

相关论文

共 31 条

[1] Observation of Fano interference in high-pressure ice VII [J].

Aoki, K ;

Yamawaki, H ;

Sakashita, M .

PHYSICAL REVIEW LETTERS, 1996, 76 (05) :784-786

[2]

Ball P., 2000, H2O: A biography of water

[3] THE DISTRIBUTION OF RINGS OF HYDROGEN-BONDED MOLECULES IN A MODEL OF LIQUID WATER [J].

BELCH, AC ;

RICE, SA .

JOURNAL OF CHEMICAL PHYSICS, 1987, 86 (10) :5676-5682

[4] Structure and phonons of the ice surface [J].

Braun, J ;

Glebov, A ;

Graham, AP ;

Menzel, A ;

Toennies, JP .

PHYSICAL REVIEW LETTERS, 1998, 80 (12) :2638-2641

[5] Surface vibrations of large water clusters by He atom scattering [J].

Brudermann, J ;

Lohbrandt, P ;

Buck, U ;

Buch, V .

PHYSICAL REVIEW LETTERS, 1998, 80 (13) :2821-2824

[6] THE ADSORPTION OF WATER ON CLEAN AND OXYGEN-DOSED RU(001) [J].

DOERING, DL ;

MADEY, TE .

SURFACE SCIENCE, 1982, 123 (2-3) :305-337

[7]

Eisenberg D., 2005, STRUCTURE PROPERTIES

[8] Raman spectroscopy of dense H2O and the transition to symmetric hydrogen bonds [J].

Goncharov, AF ;

Struzhkin, VV ;

Mao, HK ;

Hemley, RJ .

PHYSICAL REVIEW LETTERS, 1999, 83 (10) :1998-2001

[9] Structure of water clusters. The contribution of many-body forces, monomer relaxation, and vibrational zero-point energy [J].

Gregory, JK ;

Clary, DC .

JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (46) :18014-18022

[10] Bond-order potential and cluster recursion for the description of chemical bonds: Efficient real-space methods for tight-binding molecular dynamics [J].

Horsfield, AP ;

Bratkovsky, AM ;

Pettifor, DG ;

Aoki, M .

PHYSICAL REVIEW B, 1996, 53 (03) :1656-1666

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