Property influence of polyanilines on photovoltaic behaviors of dye-sensitized solar cells

被引:97
作者
Tan, SX
Zhai, J [1 ]
Xue, BF
Wan, MX
Meng, QB
Li, YL
Jiang, L
Zhu, DB
机构
[1] Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China
[2] Chinese Acad Sci, Inst Phys, State Key Lab Surface Phys, Beijing 100080, Peoples R China
关键词
D O I
10.1021/la036260m
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The influence of polyanilines (PANIs) as hole conductors on the photovoltaic behaviors of dye-sensitized solar cells is studied. The current-voltage (I-V) characteristics and the incident photon to current conversion efficiency (IPCE) curves of the devices are determined as the function of different conductivities and morphologies of PANIs. The results show that the conductivity of PANIs affects the performance of the devices greatly, and PANI with the intermediate conductivity value (3.5 S/cm) is optimum. In addition, the effects of both the film formation property and the cluster size of polyanilines on the photovoltaic behaviors of the devices are also discussed.
引用
收藏
页码:2934 / 2937
页数:4
相关论文
共 49 条
[1]   Charge transfer in photovoltaics consisting of interpenetrating networks of conjugated polymer and TiO2 nanoparticles [J].
Arango, AC ;
Carter, SA ;
Brock, PJ .
APPLIED PHYSICS LETTERS, 1999, 74 (12) :1698-1700
[2]  
Arango AC, 2000, ADV MATER, V12, P1689, DOI 10.1002/1521-4095(200011)12:22<1689::AID-ADMA1689>3.0.CO
[3]  
2-9
[4]   POLYANILINE - CONFORMATIONAL-CHANGES INDUCED IN SOLUTION BY VARIATION OF SOLVENT AND DOPING LEVEL [J].
AVLYANOV, JK ;
MIN, YG ;
MACDIARMID, AG ;
EPSTEIN, AJ .
SYNTHETIC METALS, 1995, 72 (01) :65-71
[5]   Solid-state dye-sensitized mesoporous TiO2 solar cells with high photon-to-electron conversion efficiencies [J].
Bach, U ;
Lupo, D ;
Comte, P ;
Moser, JE ;
Weissörtel, F ;
Salbeck, J ;
Spreitzer, H ;
Grätzel, M .
NATURE, 1998, 395 (6702) :583-585
[6]   A SOLID-STATE, DYE-SENSITIZED PHOTOELECTROCHEMICAL CELL [J].
CAO, F ;
OSKAM, G ;
SEARSON, PC .
JOURNAL OF PHYSICAL CHEMISTRY, 1995, 99 (47) :17071-17073
[7]   COUNTERION INDUCED PROCESSIBILITY OF CONDUCTING POLYANILINE AND OF CONDUCTING POLYBLENDS OF POLYANILINE IN BULK POLYMERS [J].
CAO, Y ;
SMITH, P ;
HEEGER, AJ .
SYNTHETIC METALS, 1992, 48 (01) :91-97
[8]   ORGANIC SOLID-STATE .8. MIXED-VALENCE FERROCENE CHEMISTRY [J].
COWAN, DO ;
LEVANDA, C ;
PARK, J ;
KAUFMAN, F .
ACCOUNTS OF CHEMICAL RESEARCH, 1973, 6 (01) :1-7
[9]   Solid-state organic/inorganic hybrid solar cells based on conjugated polymers and dye-sensitized TiO2 electrodes [J].
Gebeyehu, D ;
Brabec, CJ ;
Sariciftci, NS .
THIN SOLID FILMS, 2002, 403 :271-274
[10]   Hybrid solar cells based on dye-sensitized nanoporous TiO2 electrodes and conjugated polymers as hole transport materials [J].
Gebeyehu, D ;
Brabec, CJ ;
Sariciftci, NS ;
Vangeneugden, D ;
Kiebooms, R ;
Vanderzande, D ;
Kienberger, F ;
Schindler, H .
SYNTHETIC METALS, 2001, 125 (03) :279-287