Tandem oxidation processes using manganese dioxide: Discovery, applications, and current studies

被引：302

作者：

Taylor, RJK ^{[1
]}

Reid, M ^{[1
]}

Foot, J ^{[1
]}

Raw, SA ^{[1
]}

机构：

[1] Univ York, Dept Chem, York YO10 5DD, N Yorkshire, England

来源：

ACCOUNTS OF CHEMICAL RESEARCH | 2005年 / 38卷 / 11期

关键词：

D O I：

10.1021/ar050113t

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

One-pot processes in which alcohol oxidations are combined with further elaboration of the carbonyl intermediate are reviewed. Sequential processes are briefly discussed, but most attention is centered on tandem processes; that is, oxidations carried out in the presence of a nucleophilic trapping agent, rather than those in which the trapping agent is added after the oxidation is complete. As part of this Account, a comprehensive review of the discovery of tandem oxidation processes (TOP) will be given together with applications in alkene-forming reactions, cyclopropanations, and imine, oxime, amine, and heterocycle formation.

引用

页码：851 / 869

页数：19

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