General access to polyhydroxylated nortropane derivatives through hetero Diels-Alder cycloadditions.: Part 3.: Synthesis of natural (+)-calystegine B2

被引：41

作者：

Faitg, T

Soulié, J ^{[1
]}

Lallemand, JY

Ricard, L

机构：

[1] Ecole Polytech, DCSO, CNRS, UMR 7652, F-91128 Palaiseau, France

[2] Ecole Polytech, DCPH, CNRS, UMR 7653, F-91128 Palaiseau, France

来源：

TETRAHEDRON-ASYMMETRY | 1999年 / 10卷 / 11期

关键词：

D O I：

10.1016/S0957-4166(99)00204-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Cycloaddition of chiral nitroso derivatives with cyclohepta-1,3-diene gave one single stereoisomer with an excellent selectivity. The structures including absolute configurations have been assigned by spectroscopy and X-ray crystallography. These studies have been applied to the total synthesis of the naturally occurring calystegine B-2. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：2165 / 2174

页数：10

共 19 条

[1] OXIDATION OF ALDOSE OXIMES - FORMATION AND STRUCTURE OF HYDROXYDIAZENE OXIDE ACETALS AND PREPARATION OF HYDROXIMOLACTONES - X-RAY CRYSTAL-STRUCTURE OF 2,3-5,6-DI-O-ISOPROPYLIDENE-ALPHA-D-MANNOFURANOSYL-ONN-AZOXY 2,3-5,6-DI-O-ISOPROPYLIDENE-ALPHA-D-MANNOFURANOSIDE [J].