Enantioselective determination of chiral organochlorine compounds in biota by gas chromatography on modified cyclodextrins

被引：117

作者：

Vetter, W ^{[1
]}

Schurig, V ^{[1
]}

机构：

[1] UNIV TUBINGEN, INST ORGAN CHEM, D-72076 TUBINGEN, GERMANY

来源：

JOURNAL OF CHROMATOGRAPHY A | 1997年 / 774卷 / 1-2期

关键词：

reviews; water analysis; soil; environmental analysis; enantiomer separation; chiral stationary phases; GC; enantiomeric ratio; cyclodextrin-based stationary phases; organochlorine compounds; pesticides; polychlorinated biphenyls;

D O I：

10.1016/S0021-9673(97)00296-3

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

Approaches to the gas chromatographic enantiomer separation of chiral organochlorines (alpha-hexachlorocyclohexane, cis- and trans-chlordane, heptachlor, heptachlorepoxide, oxychlordane, o,p'-DDT, compounds of technical toxaphene and stable atropisomeric polychlorinated biphenyls) are reviewed. Chiral stationary phases based on cyclodextrin derivatives and used for the gas chromatographic enantiomer separation of the chiral organochlorines are described. Enantiomeric ratios of chiral organochlorines in technical mixtures and biological samples are reported and discussed. (C) 1997 Elsevier Science B.V.

引用

页码：143 / 175

页数：33

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