Supercritical fluid extraction of Moroccan (Timahdit) oil shale with water

被引:67
作者
El harfi, K
Bennouna, C
Mokhlisse, A
Ben chanâa, M
Lemée, L
Joffre, J
Amblès, A
机构
[1] Univ Caddi Ayyad, Chim Phys Lab, Fac Sci Marrakech, Semlalia 40001, Morocco
[2] Univ Caddi Ayyad, Lab Chim Organ Appl, Fac Sci Marrakech, Semlalia 40001, Morocco
[3] Lab Chim 12, URA CNRS 1468, F-86022 Poitiers, France
关键词
oil shale; shale oil; pyrolysis; supercritical extraction;
D O I
10.1016/S0165-2370(99)00028-5
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Timahdit oil shale was subjected to supercritical water extraction. The results reveal significant difference in oil yields and composition when compared with those obtained from conventional pyrolysis. In addition, the effect of temperature and residence time on the supercritical water extraction of oil was investigated in a set of three experiments. The results revealed that the yield and the fraction of paraffins and aromatics increase while the percentage of asphaltenes decreases as the temperature is increased from 380 to 400 degrees C. The residence time was found to affect the yield and the fraction of asphaltenes and polar compounds. (C) 1999 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:163 / 174
页数:12
相关论文
共 21 条
[1]  
BEKRI O, 1982, ANALUSIS, V8, P88
[2]  
BEKRI O, 1983, P 16 OIL SHAL S COL, P345
[3]   INVESTIGATION OF DIFFUSIONAL PHENOMENON IN THE OIL-SHALE OF TIMAHDIT (MOROCCO) - ROLE OF SEDIMENTED PLANS [J].
BELKBIR, L ;
BARKIA, H ;
GERARD, N .
THERMOCHIMICA ACTA, 1986, 103 (01) :147-150
[4]  
BENNOUNA C, 1993 E OIL SHAL S 16
[5]   UPGRADING OF DISTILLATE FRACTIONS OF TIMAHDIT MOROCCAN SHALE OIL OVER A SULFIDED NIO-MOO3/GAMMA-AL2O3 CATALYST [J].
BENYAMNA, A ;
BENNOUNA, C ;
MOREAU, C ;
GENESTE, P .
FUEL, 1991, 70 (07) :845-848
[6]  
DAHBI A, 1992, ANALUSIS, V20, P239
[7]   EXTRACTION OF COAL USING SUPERCRITICAL WATER [J].
DESHPANDE, GV ;
HOLDER, GD ;
BISHOP, AA ;
GOPAL, J ;
WENDER, I .
FUEL, 1984, 63 (07) :956-960
[8]   Effect of water vapor on the pyrolysis of the Moroccan (Tarfaya) oil shale [J].
El Harfi, K ;
Mokhlisse, A ;
Ben Chanâa, M .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 1999, 48 (02) :65-76
[9]   GAS EVOLUTION DURING ISOTHERMAL PYROLYSIS OF TIMAHDIT OIL-SHALE [J].
GABORIAUD, F ;
VANTELON, JP ;
GUELZIM, A ;
JULIEN, L .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 1991, 21 (1-2) :119-131
[10]  
Hoering T.C., 1984, Org. Geochem, V5, P267, DOI DOI 10.1016/0146-6380(84)90014-7