Nanosegregated Amorphous Composites of Calcium Carbonate and an Organic Polymer

被引:117
作者
Oaki, Yuya [1 ]
Kajiyama, Satoshi [1 ]
Nishimura, Tatsuya [1 ]
Imai, Hiroaki [2 ]
Kato, Takashi [1 ]
机构
[1] Univ Tokyo, Sch Engn, Dept Chem & Biotechnol, Bunkyo Ku, Tokyo 1138656, Japan
[2] Keio Univ, Fac Sci & Technol, Dept Appl Chem, Kohoku Ku, Yokohama, Kanagawa 2238522, Japan
关键词
D O I
10.1002/adma.200800773
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Transparent and stable composites of calcium carbonate and an acidic macromolecule are obtained at mild conditions. The nanosegregated structure is formed in the amorphous composite materials in the bulk and thin-film states. The transparent, stable, and crack-free thin films might be beneficial for coating of materials. Transparent and stable composites
引用
收藏
页码:3633 / +
页数:6
相关论文
共 41 条
[1]   CONTROL AND DESIGN PRINCIPLES IN BIOLOGICAL MINERALIZATION [J].
ADDADI, L ;
WEINER, S .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1992, 31 (02) :153-169
[2]   Taking advantage of disorder: Amorphous calcium carbonate and its roles in biomineralization [J].
Addadi, L ;
Raz, S ;
Weiner, S .
ADVANCED MATERIALS, 2003, 15 (12) :959-970
[3]   Direct fabrication of large micropatterned single crystals [J].
Aizenberg, J ;
Muller, DA ;
Grazul, JL ;
Hamann, DR .
SCIENCE, 2003, 299 (5610) :1205-1208
[4]   Formation of single-crystalline aragonite tablets/films via an amorphous precursor [J].
Amos, Fairland F. ;
Sharbaugh, Denise M. ;
Talham, Daniel R. ;
Gower, Laurie B. ;
Fricke, Marc ;
Volkmer, Dirk .
LANGMUIR, 2007, 23 (04) :1988-1994
[5]   Promises and problems of mesoscale materials chemistry or why meso? [J].
Antonietti, M ;
Ozin, GA .
CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (01) :28-41
[6]  
Bauerlein E., 2007, HDB BIOMINERALIZATIO
[7]   Amorphous calcium carbonate transforms into calcite during sea urchin larval spicule growth [J].
Beniash, E ;
Aizenberg, J ;
Addadi, L ;
Weiner, S .
PROCEEDINGS OF THE ROYAL SOCIETY B-BIOLOGICAL SCIENCES, 1997, 264 (1380) :461-465
[8]   Organic inorganic hybrid materials [J].
Chujo, Y .
CURRENT OPINION IN SOLID STATE & MATERIALS SCIENCE, 1996, 1 (06) :806-811
[9]   Higher-order organization by mesoscale self-assembly and transformation of hybrid nanostructures [J].
Cölfen, H ;
Mann, S .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (21) :2350-2365
[10]   Mesocrystals:: Inorganic superstructures made by highly parallel crystallization and controlled alignment [J].
Cölfen, H ;
Antonietti, M .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (35) :5576-5591