Effect of PTFE content on the performance of a Direct Methanol fuel cell

被引:24
作者
Krishnamurthy, Balaji [1 ]
Deepalochani, S. [1 ]
机构
[1] Adv Res Ctr Powder Met & New Mat, Ctr Fuel Cell Technol, Chennai 600100, Tamil Nadu, India
关键词
Platinum utilization; Cyclic voltammetry; Nafion; PTFE; GAS-DIFFUSION LAYER; HYDROPHOBIC POLYMER CONTENT; WATER TRANSPORT; ELECTRODES; MORPHOLOGY; MEMBRANES; CROSSOVER; BACKING; DMFC;
D O I
10.1016/j.ijhydene.2008.09.093
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Polytetrafluroethylene (PTFE) plays a key role in the performance of a Direct Methanol fuel cell. The presence of PTFE content in the backing layer and the microporous layer affects the performance of a Direct Methanol fuel cell independently. PTFE content is found to affect the catalyst utilization values and cell impedance values. A 20% PTFE content is found to be optimal in the cathode backing layer and cathode microporous layer. The performance of a Direct Methanol fuel cell is found to be more sensitive to the PTFE content in the anode microporous layer. (C) 2008 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:446 / 452
页数:7
相关论文
共 29 条
[1]  
ANTOLINI E, 2002, J APPL ELECTROCHEM, P3810
[2]   Effects of membrane electrode assembly components on proton exchange membrane fuel cell performance [J].
Bayrakceken, Ayse ;
Erkan, Serdar ;
Turker, Lemi ;
Eroglu, Inci .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2008, 33 (01) :165-170
[3]   Water-neutral micro direct-methanol fuel cell (DMFC) for portable applications [J].
Blum, A ;
Duvdevani, T ;
Philosoph, M ;
Rudoy, N ;
Peled, E .
JOURNAL OF POWER SOURCES, 2003, 117 (1-2) :22-25
[4]   Influence of the PTFE content in the diffusion layer of low-Pt loading electrodes for polymer electrolyte fuel cells [J].
Giorgi, L ;
Antolini, E ;
Pozio, A ;
Passalacqua, E .
ELECTROCHIMICA ACTA, 1998, 43 (24) :3675-3680
[5]   Performance and methanol permeation of direct methanol fuel cells:: dependence on operating conditions and on electrode structure [J].
Gogel, V ;
Frey, T ;
Zhu, YS ;
Friedrich, KA ;
Jörissen, L ;
Garche, J .
JOURNAL OF POWER SOURCES, 2004, 127 (1-2) :172-180
[6]  
KRISHNAMURTHY B, 2008, FUEL CELLS JUL
[7]  
LAJOS G, 2007, ELECTROCHEM SOLID ST, V10, pB150
[8]   Ionic conductivity of PEMFC electrodes - Effect of Nafion loading [J].
Li, GC ;
Pickup, PG .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (11) :C745-C752
[9]   Effects of hydrophobic polymer content in GDL on power performance of a PEM fuel cell [J].
Lim, C ;
Wang, CY .
ELECTROCHIMICA ACTA, 2004, 49 (24) :4149-4156
[10]   Effect of thickness and hydrophobic polymer content of the gas diffusion layer on electrode flooding level in a PEMFC [J].
Lin, GY ;
Nguyen, TV .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2005, 152 (10) :A1942-A1948