Iron hydrogenase active site mimic holding a proton and a hydride

被引：163

作者：

Schwartz, L

Eilers, G

Eriksson, L

Gogoll, A

Lomoth, R

Ott, S

机构：

[1] Uppsala Univ, Dept Phys Chem, BMC, S-75123 Uppsala, Sweden

[2] Univ Stockholm, Arrhenius Lab, Dept Organ Chem, S-10691 Stockholm, Sweden

[3] Univ Stockholm, Arrhenius Lab, Dept Struct Chem, S-10691 Stockholm, Sweden

[4] Uppsala Univ, Dept Chem, BMC, S-75123 Uppsala, Sweden

来源：

CHEMICAL COMMUNICATIONS | 2006年 / 05期

关键词：

D O I：

10.1039/b514280f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first model of the iron hydrogenase active site has been prepared which concomitantly carries a proton and a hydride; the title species was characterized by IR and NMR spectroscopy and is reduced at more positive potential than any other mimic of this kind.

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收藏

页码：520 / 522

页数：3

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