Carbon nanotubes contain metal impurities which are responsible for the "electrocatalysis" seen at some nanotube-modified electrodes

被引:618
作者
Banks, CE
Crossley, A
Salter, C
Wilkins, SJ
Compton, RG
机构
[1] Univ Oxford, Phys & Theoret Chem Lab, Oxford OX1 3QZ, England
[2] Univ Oxford, Dept Mat, Oxford OX1 3PH, England
关键词
carbon nanotubes; electrocatalysis; electrochemistry; oxidation; pyrolytic graphite electrodes;
D O I
10.1002/anie.200600033
中图分类号
O6 [化学];
学科分类号
0703 [化学];
摘要
Its all done with metals: The title statement is confirmed by comparing the electrocatalytic oxidation of hydrazine at a basal-plane pyrolytic-graphite (BPPG) electrode treated with iron (III) (blue) with that at a multiwalled-carbon-nanotube (MW-CNT)-modified BPPG electrode (red) and at an edge-plane pyrolytic graphite electrode (black; ••••• and -•-• are the responses of iron(III)-treated and MW-CNT-modified BPPG electrode, respectively, in the absence of hydrazine). (Figure Presented) © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:2533 / 2537
页数:5
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