Fourier transform measurement of NO2 absorption cross-section in the visible range at room temperature

被引:117
作者
Vandaele, AC [1 ]
Hermans, C [1 ]
Simon, PC [1 ]
VanRoozendael, M [1 ]
Guilmot, JM [1 ]
Carleer, M [1 ]
Colin, R [1 ]
机构
[1] FREE UNIV BRUSSELS,CHIM PHYS LAB,B-1050 BRUSSELS,BELGIUM
关键词
Fourier transform spectroscopy; NO2; absorption cross-sections; differential absorption cross-sections; visible; stratospheric and tropospheric measurements;
D O I
10.1007/BF00053797
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
New laboratory measurements of NO2 absorption cross-section were performed using a Fourier transform spectrometer at 2 and 16 cm(-1) (0.03 and 0.26 nm at 400 nm) in the visible range (380-830 nm) and at room temperature. The use of a Fourier transform spectrometer leads to a very accurate wavenumber scale (0.005 cm(-1), 8 x 10(-5) nm at 400 nm). The uncertainty on the new measurements is better than 4%. Absolute and differential cross-sections are compared with published data, giving an agreement ranging from 2 to 5% for the absolute values. The discrepancies in the differential cross-sections can however reach 18%. The influence of the cross-sections on the ground-based measurement of the stratospheric NO2 total amount is also investigated.
引用
收藏
页码:289 / 305
页数:17
相关论文
共 24 条
[1]   NEW MEASUREMENTS OF THE NO2 ABSORPTION CROSS-SECTION IN THE 440-NM TO 460-NM REGION AND ESTIMATES OF THE NO2-N2O4 EQUILIBRIUM-CONSTANT [J].
AMORUSO, A ;
CRESCENTINI, L ;
FIOCCO, G ;
VOLPE, M .
JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1993, 98 (D9) :16857-16863
[2]   EXTINCTION COEFFICIENTS OF NO2 AND N2O4 [J].
BASS, AM ;
LEDFORD, AE ;
LAUFER, AH .
JOURNAL OF RESEARCH OF THE NATIONAL BUREAU OF STANDARDS SECTION A-PHYSICS AND CHEMISTRY, 1976, 80 (02) :143-166
[3]   Intercomparison of instruments for tropospheric measurements using differential optical absorption spectroscopy [J].
CamyPeyret, C ;
Bergqvist, B ;
Galle, B ;
Carleer, M ;
Clerbaux, C ;
Colin, R ;
Fayt, C ;
Goutail, F ;
NunesPinharanda, M ;
Pommereau, JP ;
Hausmann, M ;
Platt, U ;
Pundt, I ;
Rudolph, T ;
Hermans, C ;
Simon, PC ;
Vandaele, AC ;
Plane, JMC ;
Smith, N .
JOURNAL OF ATMOSPHERIC CHEMISTRY, 1996, 23 (01) :51-80
[4]  
CHANACE KV, 1990, ATMOSPHERIC SPECTROS, P186
[5]   THE NO2 ABSORPTION-SPECTRUM .2. ABSORPTION CROSS-SECTIONS AT LOW-TEMPERATURES IN THE 400-500 NM REGION [J].
COQUART, B ;
JENOUVRIER, A ;
MERIENNE, MF .
JOURNAL OF ATMOSPHERIC CHEMISTRY, 1995, 21 (03) :251-261
[7]   VISIBLE-ULTRAVIOLET ABSORPTION CROSS-SECTIONS FOR NO2 AS A FUNCTION OF TEMPERATURE [J].
DAVIDSON, JA ;
CANTRELL, CA ;
MCDANIEL, AH ;
SHETTER, RE ;
MADRONICH, S ;
CALVERT, JG .
JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1988, 93 (D6) :7105-7112
[8]   DIFFERENTIAL OPTICAL-ABSORPTION SPECTROSCOPY (DOAS) SYSTEM FOR URBAN ATMOSPHERIC-POLLUTION MONITORING [J].
EDNER, H ;
RAGNARSON, P ;
SPANNARE, S ;
SVANBERG, S .
APPLIED OPTICS, 1993, 32 (03) :327-333
[9]   DIFFERENTIAL OPTICAL-ABSORPTION SPECTROMETER FOR MEASUREMENT OF TROPOSPHERIC POLLUTANTS [J].
EVANGELISTI, F ;
BARONCELLI, A ;
BONASONI, P ;
GIOVANELLI, G ;
RAVEGNANI, F .
APPLIED OPTICS, 1995, 34 (15) :2737-2744
[10]   SEPARATION OF THE ABSORPTION SPECTRA OF NO2 AND N2O4 IN THE RANGE OF 2400-5000A [J].
HALL, TC ;
BLACET, FE .
JOURNAL OF CHEMICAL PHYSICS, 1952, 20 (11) :1745-1749