Electron transport in nanostructured metal-oxide semiconductors

被引:52
作者
Anta, Juan A. [1 ]
机构
[1] Univ Pablo de Olavide, Area Quim Fis, Seville, Spain
关键词
Nanostructured semiconductors; Charge transport; Solar cells; Photocatalysis; Random walk numerical simulation; SENSITIZED SOLAR-CELLS; HIGH-EFFICIENCY; TIO2; FILMS; DIFFUSION; RECOMBINATION; STATE; ZNO; COLLECTION; SIMULATION; GENERATION;
D O I
10.1016/j.cocis.2012.02.003
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Nanostructured films of metal-oxide semiconductors are the focus of intensive research nowadays due to their applications in the current quest for new sources of clean energy. Metal-oxides like TiO2 and ZnO can be used to make efficient photoanodes for photoelectrochemical solar cells and nanostructured substrates for photocatalytic production of non-polluting fuels. In these applications electron transport through the nanostructure is crucial to achieve a good photon-to-electron quantum efficiency. In this paper the current knowledge of the electron transport mechanisms that take place in these systems is reviewed, highlighting the influence of energy and morphological disorder on the efficacy of the transport process. A special connection is made between the specificity of the electron transport in these systems and their applications in solar cells and photocatalytic devices. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码:124 / 131
页数:8
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