Evaluation of the effect of ruthenium oxide on the properties of composite electrodes used in cathodic protection

被引:8
作者
Darowicki, K [1 ]
Janicki, S [1 ]
机构
[1] Gdansk Tech Univ, Fac Chem, Dept Anticorros Protect, PL-80952 Gdansk, Poland
关键词
cathodic protection; conducting polymeric composites; potentiodynamic polarisation; EIS;
D O I
10.1016/S0010-938X(98)00177-2
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Results have been presented of potentiodynamic and impedance investigations of conducting polymeric composites based on the polyethylene matrix with addition of DuPont vinyl acetate (Elvax 450). High conducting carbon black was the main conducting component of investigated polymeric composites. Improvement of the current output of composite electrodes was realised by introduction of active ruthenium dioxide. Statistical analysis was carried out of potentiodynamic dependencies allowing determination of relations of the current output of designed electrodes in the function of the percentage of introduced oxide. An improvement of electrochemical parameters has been shown characterising polymeric composites with increase of the percentage of ruthenium oxide. (C) 1999 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:1165 / 1173
页数:9
相关论文
共 15 条
[1]   PROPERTIES OF THERMALLY PREPARED IRIDIUM DIOXIDE ELECTRODES [J].
ARDIZZONE, S ;
CARUGATI, A ;
TRASATTI, S .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1981, 126 (1-3) :287-292
[2]   IMPEDANCE OF HYDRATED IRIDIUM OXIDE ELECTRODES [J].
AURIANBLAJENI, B ;
BEEBE, X ;
RAUH, RD ;
ROSE, TL .
ELECTROCHIMICA ACTA, 1989, 34 (06) :795-802
[3]   Differential analysis of impedance data [J].
Darowicki, K .
ELECTROCHIMICA ACTA, 1998, 43 (16-17) :2281-2285
[4]   Evaluation of the current output of polymer anodes used in cathodic protection [J].
Darowicki, K ;
Orlikowski, J ;
Walaszkowski, J .
CORROSION SCIENCE, 1998, 40 (06) :931-937
[5]  
DAROWICKI K, IN PRESS J ELECTROCH
[6]   RUTHENIUM DIOXIDE - NEW ELECTRODE MATERIAL .1. BEHAVIOR IN ACID SOLUTIONS OF INERT ELECTROLYTES [J].
GALIZZIOLI, D ;
TANTARDINI, F ;
TRASATTI, S .
JOURNAL OF APPLIED ELECTROCHEMISTRY, 1974, 4 (01) :57-67
[7]  
GIBSON WF, 1993, MATER PERFORMANCE, V32, P24
[8]  
SHREIER L, 1994, CORROSION, V2
[9]   PHYSICAL ELECTROCHEMISTRY OF CERAMIC OXIDES [J].
TRASATTI, S .
ELECTROCHIMICA ACTA, 1991, 36 (02) :225-241
[10]  
TRASATTI S, 1981, ELECT CONDUCTIVE M B