Interaction of NiO with yttria-stabilized zirconia

被引：74

作者：

Kuzjukevics, A ^{[1
]}

Linderoth, S ^{[1
]}

机构：

[1] LAS,INST INORGAN CHEM,LV-2169 RIGA,LATVIA

来源：

SOLID STATE IONICS | 1997年 / 93卷 / 3-4期

关键词：

yttria-stabilized zirconia; nickel oxide; solubility; ultrafine powders; plasma synthesis;

D O I：

10.1016/S0167-2738(96)00529-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

As-prepared and heat treated plasma-produced 8 and 10 mol% yttria-stabilized zirconia (YSZ) powders doped with 0, 5, 10 and 75 mol% NiO have been investigated by XRD. The as-prepared powders are mixtures of metastable tetragonal and cubic phases but they transform to a single YSZ phase upon heat treatment above 1200 degrees C. The solubility of NiO in yttria-stabilized zirconia is less than 2 mol% at 1600 degrees C and varies little within the investigated yttria concentration range. The solubility increases with increasing temperature and the total NiO concentration. The activation energy of the solubility is about 0.25 eV.

引用

页码：255 / 261

页数：7

共 17 条

[1] ALPERINE S, 1992, 37 ASME C GAS TURB A, P1
[2] EFFECT OF NIO DISSOLUTION ON THE TRANSFORMATION OF PLASMA-SPRAYED Y-PSZ
CHEN, S
SHEN, P
[J]. MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 1989, 114 : 159 - 165
[3] CHEN SY, 1992, MAT SCI ENG A-STRUCT, V158, P251
[4] STABILITY OF CUBIC ZRO2 (10 MOL-PERCENT Y2O3) WHEN ALLOYED WITH NIO, AL2O3 OR TIO2 - IMPLICATIONS TO SOLID ELECTROLYTES AND CERMETS
CHEN, SY
DENG, WH
SHEN, PY
[J]. MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 1994, 22 (2-3): : 247 - 255
[5] KINETICS AND MECHANISM OF THE REDUCTION OF NICKEL-OXIDE IN ALIGNED NICKEL-OXIDE ZIRCONIA AND NICKEL-OXIDE YTTRIA EUTECTIC STRUCTURES
DHALENNE, G
BONVALOT, B
REVCOLEVSCHI, A
MILLOT, F
[J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1990, 73 (06) : 1524 - 1528
[6] GRABIS J, 1996, UNPUB J MAT SCI
[7] THE DISPLACIVE CUBIC-]TETRAGONAL TRANSFORMATION IN ZRO2 ALLOYS
HEUER, AH
CHAIM, R
LANTERI, V
[J]. ACTA METALLURGICA, 1987, 35 (03): : 661 - 666
[8] LATTICE-PARAMETERS AND DENSITY FOR Y2O3-STABILIZED ZRO2
INGEL, RP
LEWIS, D
[J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1986, 69 (04) : 325 - 332
[9] LATTICE-PARAMETERS, IONIC CONDUCTIVITIES, AND SOLUBILITY LIMITS IN FLUORITE-STRUCTURE HF-4+O2, ZR-4+O2, CE-4+O2, TH-4+O2, V-4+O2 OXIDE SOLID-SOLUTIONS
KIM, DJ
[J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1989, 72 (08) : 1415 - 1421
[10] Characterization of yttria-doped zirconia powders produced by plasma-chemical method
Kuzjukevics, A
Linderoth, S
Grabis, J
[J]. SOLID STATE IONICS, 1996, 92 (3-4) : 253 - 260

← 1 2 →